Formation of an icosahedral quasicrystalline phase in Zr65Al7.5Ni10M17.5 (M = Pd, Au or Pt) alloys

被引：78

作者：

Inoue, A ^{[1
]}

Saida, J

Matsushita, M

Sakurai, T

机构：

[1] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan

[2] Japan Sci & Technol Corp, Exploratory Res Adv Technol, Inoue Superliquid Glass Project, Sendai, Miyagi 9820807, Japan

来源：

MATERIALS TRANSACTIONS JIM | 2000年 / 41卷 / 02期

关键词：

zirconium-based quasicrystalline alloy; glass transition; metastable icosahedral phase; two-stage crystallization; nanograin structure;

D O I：

10.2320/matertrans1989.41.362

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An icosahedral (I) phase was found to be formed as a metastable phase in the crystallization process of amorphous Zr65Al7.5Ni10M17.5 (M = Pd, An or Pt) alloys. The three amorphous alloys show an endothermic reaction due to the glass transition, followed by two exothermic peaks. The first exothermic peak is due to the precipitation of an I-phase and the second one results from the transition from the I to crystalline mixed phases of Zr4Al3 + Zr2Ni + Zr2Pd (Zr2Au or ZrPt). The I-phase consists of fine grains with a size of about 10 nm and no distinct residual amorphous phase is seen. The formation of the I-phase in the new Zr-based alloy systems with a large supercooled liquid region and high glass-forming ability is important for the future development of bulk quasicrystalline alloys as basic science and engineering materials.

引用

页码：362 / 365

页数：4

共 18 条

[1]

BOER FR, 1989, COHESION METALS, P291

[2] Quasicrystals in a partially devitrified Zr65Al7.5Ni10Cu12.5Ag5 bulk metallic glass [J].

Chen, MW ;

Zhang, T ;

Inoue, A ;

Sakai, A ;

Sakurai, T .

APPLIED PHYSICS LETTERS, 1999, 75 (12) :1697-1699

[3] Crystallization behavior and phase formation in Zr-Al-Cu-Ni metallic glass containing oxygen [J].

Eckert, J ;

Mattern, N ;

Zinkevitch, M ;

Seidel, M .

MATERIALS TRANSACTIONS JIM, 1998, 39 (06) :623-632

[4]

GOLDMAN AI, 1997, WORLD SCI, P1

[5] High strength and good ductility of bulk quasicrystalline base alloys in Zr65Al7.5Ni10Cu17.5-xPdx system [J].

Inoue, A ;

Zhang, T ;

Saida, J ;

Matsushita, M ;

Chen, MW ;

Sakurai, T .

MATERIALS TRANSACTIONS JIM, 1999, 40 (10) :1137-1143

[6] RETRACTED: Mechanical properties of bulk amorphous Zr-Al-Cu-Ni-Ag alloys containing nanoscale quasicrystalline particles (Retracted Article) [J].

Inoue, A ;

Zhang, T ;

Chen, MW ;

Sakurai, T .

MATERIALS TRANSACTIONS JIM, 1999, 40 (12) :1382-1389

[7] HIGH-STRENGTH BULK AMORPHOUS-ALLOYS WITH LOW CRITICAL COOLING RATES [J].

INOUE, A .

MATERIALS TRANSACTIONS JIM, 1995, 36 (07) :866-875

[8] Formation of icosahedral quasicrystalline phase in Zr-Al-Ni-Cu-M (M = Ag, Pd, Au or Pt) systems [J].

Inoue, A ;

Zhang, T ;

Saida, J ;

Matsushita, M ;

Chen, MW ;

Sakurai, T .

MATERIALS TRANSACTIONS JIM, 1999, 40 (10) :1181-1184

[9] STABILITY AND TRANSFORMATION TO CRYSTALLINE PHASES OF AMORPHOUS ZR-AL-CU ALLOYS WITH SIGNIFICANT SUPERCOOLED LIQUID REGION [J].

INOUE, A ;

KAWASE, D ;

TSAI, AP ;

ZHANG, T ;

MASUMOTO, T .

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1994, 178 (1-2) :255-263

[10] ZR-AL-NI AMORPHOUS-ALLOYS WITH HIGH GLASS-TRANSITION TEMPERATURE AND SIGNIFICANT SUPERCOOLED LIQUID REGION [J].

INOUE, A ;

ZHANG, T ;

MASUMOTO, T .

MATERIALS TRANSACTIONS JIM, 1990, 31 (03) :177-183

← 1 2 →