A functionalized renewable carbon-based surface for sensor development

被引:6
作者
Silva, Martin K. L. [1 ]
Leao, Alcides L. [1 ]
Sain, Mohini [2 ,3 ]
Cesarino, Ivana [1 ]
机构
[1] Sao Paulo State Univ UNESP, Sch Agr, Ave Univ 3780, BR-18610034 Botucatu, SP, Brazil
[2] Univ Toronto, Ctr Biocomposites & Biomat Proc, Fac Forestry, Toronto, ON, Canada
[3] Univ Toronto, Dept Mech & Ind Engn, Toronto, ON, Canada
基金
巴西圣保罗研究基金会;
关键词
Renewable carbon; Surface modification; Acid treatment; Electrochemical sensors; Low-cost; VOLTAMMETRIC DETERMINATION; ACTIVATED CARBON; SENSITIVE DETECTION; BIOCHAR; NANOPARTICLES; GRAPHENE; ANTIMONY; ACID; CHEMISTRY; OXIDATION;
D O I
10.1007/s10008-020-04882-x
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper describes the surface modification of glassy carbon (GC) electrodes with a bamboo-based renewable carbon (RC) before and after an acid functionalization procedure with a sulfonitric solution (1:3 HNO3/H2SO4). The morphology and structural characterization indicate an increase of functional groups in the functionalized renewable carbon (RCF) surface. The enhanced electroanalytical properties of RC and RCF were evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) in two different setups, in the presence of the redox couple ([Fe(CN)(6)](3-/4-)) and escitalopram (EST). The results revealed an enhancement for the electrochemical responses of both inorganic and organic compounds in the electrolyte. Therefore, the use of new carbon-based materials such as renewable carbon for development of electrochemical sensors brings a fresh approach to low-cost device development.
引用
收藏
页码:1093 / 1099
页数:7
相关论文
共 46 条
[1]   Sensitive voltammetric determination of lead released from ceramic dishes by using of bismuth nanostructures anchored on biochar [J].
Agustini, Deonir ;
Mangrich, Antonio Salvio ;
Bergamini, Marcio F. ;
Marcolino-Junior, Luiz Humberto .
TALANTA, 2015, 142 :221-227
[2]   Utilization of wood biomass char in a direct carbon fuel cell (DCFC) system [J].
Ahn, Seong Yool ;
Eom, Seong Yong ;
Rhie, Young Hoon ;
Sung, Yon Mo ;
Moon, Cheor Eon ;
Choi, Gyung Min ;
Kim, Duck Jool .
APPLIED ENERGY, 2013, 105 :207-216
[3]   Chemically engineered biochar - Effect of concentration and type of modifier on sorption and structural properties of biochar from wood waste [J].
Boguta, Patrycja ;
Sokolowska, Zofia ;
Skic, Kamil ;
Tomczyk, Agnieszka .
FUEL, 2019, 256
[4]   Electrochemical oxidation of sulfamethazine on a glassy carbon electrode modified with graphene and gold nanoparticles [J].
Cesarino, Ivana ;
Simoes, Rafael Plana ;
Lavarda, Francisco Carlos ;
Batagin-Neto, Augusto .
ELECTROCHIMICA ACTA, 2016, 192 :8-14
[5]   Carbon nanotubes modified with antimony nanoparticles in a paraffin composite electrode: Simultaneous determination of sulfamethoxazole and trimethoprim [J].
Cesarino, Ivana ;
Cesarino, Vivian ;
Lanza, Marcos R. V. .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 188 :1293-1299
[6]   Electrochemical degradation of benzene in natural water using silver nanoparticle-decorated carbon nanotubes [J].
Cesarino, Ivana ;
Cesarino, Vivian ;
Moraes, Fernando C. ;
Ferreira, Tanare C. R. ;
Lanza, Marcos R. V. ;
Mascaro, Lucia H. ;
Machado, Sergio A. S. .
MATERIALS CHEMISTRY AND PHYSICS, 2013, 141 (01) :304-309
[7]   Biosensor Based on Electrocodeposition of Carbon Nanotubes/Polypyrrole/Laccase for Neurotransmitter Detection [J].
Cesarino, Ivana ;
Galesco, Heloisa V. ;
Moraes, Fernando C. ;
Lanza, Marcos R. V. ;
Machado, Sergio A. S. .
ELECTROANALYSIS, 2013, 25 (02) :394-400
[8]   Evaluation of Reduced Graphene Oxide Modified with Antimony and Copper Nanoparticles for Levofloxacin Oxidation [J].
Da Silva, Martin K. L. ;
Simoes, Rafael Plana ;
Cesarino, Ivana .
ELECTROANALYSIS, 2018, 30 (09) :2066-2076
[9]   Textural characteristics, surface chemistry and oxidation of activated carbon [J].
Daud, Wan Mohd Ashri Wan ;
Houshamnd, Amir Hossein .
JOURNAL OF NATURAL GAS CHEMISTRY, 2010, 19 (03) :267-279
[10]   The use of activated biochar for development of a sensitive electrochemical sensor for determination of methyl parathion [J].
de Oliveira, Paulo Roberto ;
Kalinke, Cristiane ;
Gogola, Jeferson Luiz ;
Mangrich, Antonio Salvio ;
Marcolino Junior, Luiz Humberto ;
Bergamini, Marcio F. .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2017, 799 :602-608