Photocatalytic performance of a visible light TiO2 photocatalyst prepared by a surface chemical modification process

被引:144
作者
Chen, Feng [1 ]
Zou, Weiwei
Qu, Wenwu
Zhang, Jinlong
机构
[1] E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China
关键词
Photocatalysis; TiO2; Surface chemical modification; Visible light; Toluene 2,4-diisocyanate; INTERFACIAL ELECTRON-TRANSFER; PHOTOASSISTED DEGRADATION; DYE POLLUTANTS; NANOPARTICLES; INJECTION; MECHANISM; NITROGEN; IRRADIATION; DYNAMICS; RECOMBINATION;
D O I
10.1016/j.catcom.2009.04.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A visible light TiO2 photocatalyst was prepared by a surface chemical modification process with toluene 2,4-diisocyanate (TDI). Because of the LMCT excition of the surface complex, the as-prepared TiO2-TDI has an obvious absorption in visible region. TiO2-TDI photocatalyst presented a satisfactory photostability and a high photocatalytic performance for the degradation of organics. The turnover number of the photocatalyst for 2,4-dichlorophenol photodegradation reached 15.43 after five times recycled under visible light irradiation. (C) 2009 Elsevier B. V. All rights reserved.
引用
收藏
页码:1510 / 1513
页数:4
相关论文
共 27 条
[1]   Enhanced photocatalytic activity of zeolite-encapsulated TiO2 clusters by complexation with organic additives and N-doping [J].
Alvaro, M ;
Carbonell, E ;
Fornés, V ;
García, H .
CHEMPHYSCHEM, 2006, 7 (01) :200-205
[2]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[3]   Highly enhanced photoreductive degradation of perchlorinated compounds on dye-sensitized metal/TiO2 under visible light [J].
Bae, E ;
Choi, W .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (01) :147-152
[4]   Effects of surface anchoring groups (Carboxylate vs phosphonate) in ruthenium-complex-sensitized TiO2 on visible light reactivity in aqueous suspensions [J].
Bae, EY ;
Choi, WY ;
Park, JW ;
Shin, HS ;
Kim, SB ;
Lee, JS .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (37) :14093-14101
[5]   Interfacial electron-transfer dynamics in Ru(tcterpy)(NCS)3-sensitized TiO2 nanocrystalline solar cells [J].
Bauer, C ;
Boschloo, G ;
Mukhtar, E ;
Hagfeldt, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (49) :12693-12704
[6]   Photoinduced ultrafast dye-to-semiconductor electron injection from nonthermalized and thermalized donor states [J].
Benkö, G ;
Kallioinen, J ;
Korppi-Tommola, JEI ;
Yartsev, AP ;
Sundström, V .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (03) :489-493
[7]   Effect of transition metal ions on the TiO2-assisted photodegradation of dyes under visible irradiation:: A probe for the interfacial electron transfer process and reaction mechanism [J].
Chen, CC ;
Li, XZ ;
Ma, WH ;
Zhao, JC ;
Hidaka, H ;
Serpone, N .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (02) :318-324
[8]  
Chen YY, 2005, INT J MOL MED, V16, P85
[9]   Visible light activity of TiO2 for the photoreduction of CCl4 and Cr(VI) in the presence of nonionic surfactant (Brij) [J].
Cho, YM ;
Kyung, H ;
Choi, W .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 52 (01) :23-32
[10]   THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS [J].
CHOI, WY ;
TERMIN, A ;
HOFFMANN, MR .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (51) :13669-13679