Arene-ruthenium(II) complexes with hydrophilic P-donor ligands: versatile catalysts in aqueous media

被引：54

作者：

Crochet, Pascale ^{[1
]}

Cadierno, Victorio ^{[1
]}

机构：

[1] Univ Oviedo, Fac Quim,Unidad Asoc CSIC, Ctr Innovac Quim Avanzada ORFEO CINQA,Lab Compues, Inst Univ Quim Organomet Enrique Moles,Dept Quim, E-33006 Oviedo, Spain

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 33期

关键词：

ARENE-RUTHENIUM COMPLEXES; TRANSITION-METAL-COMPLEXES; HIGHLY EFFICIENT CATALYSTS; H BOND ACTIVATION; ALLYLIC ALCOHOLS; NITRILE HYDRATION; SELECTIVE HYDRATION; TERMINAL ALKYNES; MECHANISTIC INVESTIGATIONS; ASYMMETRIC HYDROGENATION;

D O I：

10.1039/c4dt01494d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the last few years there has been increasing interest in the use of water as a reaction medium for catalysis, and therefore in designing water-soluble transition-metal catalysts. Half-sandwich (eta(6)-arene)-ruthenium(II) complexes are a versatile and well-known family of ruthenium compounds that exhibit a rich catalytic and coordination chemistry. This Perspective article focuses on the catalytic applications in aqueous media of (eta(6)-arene)-ruthenium(II) complexes containing water-soluble phosphines, and related hydrophilic P-donor ligands.

引用

页码：12447 / 12462

页数：16