Rheological Studies of PMMA-PVC Based Polymer Blend Electrolytes with LiTFSI as Doping Salt

被引：35
|
作者：
Liew, Chiam-Wen [1 ]
Durairaj, R. [2 ]
Ramesh, S. [1 ]
机构：
[1] Univ Malaya, Dept Phys, Ctr Ion, Fac Sci, Kuala Lumpur 59100, Malaysia
[2] Univ Tunku Abdul Rahman, Fac Sci & Engn, Dept Mech & Mat Engn, Kuala Lumpur, Malaysia
来源：
PLOS ONE | 2014年 / 9卷 / 07期
关键词：
MECHANICAL-PROPERTIES; FUMED SILICA; IONIC LIQUID; CONDUCTIVITY; STABILITY; GELS;
D O I：
10.1371/journal.pone.0102815
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
In this research, two systems are studied. In the first system, the ratio of poly (methyl methacrylate) (PMMA) and poly (vinyl chloride) (PVC) is varied, whereas in the second system, the composition of PMMA-PVC polymer blends is varied with dopant salt, lithium bis (trifluoromethanesulfonyl) imide (LiTFSI) with a fixed ratio of 70 wt% of PMMA to 30 wt% of PVC. Oscillation tests such as amplitude sweep and frequency sweep are discussed in order to study the viscoelastic properties of samples. Elastic properties are much higher than viscous properties within the range in the amplitude sweep and oscillatory shear sweep studies. The crossover of G' and G '' is absent. Linear viscoelastic (LVE) range was further determined in order to perform the frequency sweep. However, the absence of viscous behavior in the frequency sweep indicates the solid-like characteristic within the frequency regime. The viscosity of all samples is found to decrease as shear rate increases.
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页数：11
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