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Isobaric vapor-liquid equilibria for water plus acetic acid plus potassium acetate
被引:6
作者:
Vercher, E
[1
]
Orchillés, AV
[1
]
Vázquez, MI
[1
]
Martínez-Andreu, AA
[1
]
机构:
[1] Univ Valencia, Escuela Tecn Super Ingn, Dept Ingn Quim, E-46100 Burjassot, Valencia, Spain
关键词:
D O I:
10.1021/je034169e
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
Isobaric vapor-liquid equilibria for water + acetic acid + potassium acetate at different salt concentrations as well as for solvent + potassium acetate binary mixtures have been obtained at 100 kPa. Potassium acetate is more effective in the salting-out effect (on water) than lithium and sodium acetates. The eNRTL-CT model, which is a combination of electrolyte nonrandom two-liquid and chemical theory models, has been used to fit the experimental data. The binary parameters of the model have been obtained from the experimental binary vapor-liquid equilibria which have been used to suitably reproduce the vaporliquid equilibria (VLE) for water + acetic acid + potassium acetate ternary system.
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页码:566 / 569
页数:4
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