Review of magnesium hydride-based materials: development and optimisation

被引：301

作者：

Crivello, J. -C. ^{[1
]}

Dam, B. ^{[2
]}

Denys, R. V. ^{[3
]}

Dornheim, M. ^{[5
]}

Grant, D. M. ^{[6
]}

Huot, J. ^{[7
]}

Jensen, T. R. ^{[8
,9
]}

de Jongh, P. ^{[10
]}

Latroche, M. ^{[1
]}

Milanese, C. ^{[11
,12
]}

Milcius, D. ^{[13
]}

Walker, G. S. ^{[6
]}

Webb, C. J. ^{[14
]}

Zlotea, C. ^{[1
]}

Yartys, V. A. ^{[3
,4
]}

机构：

[1] Univ Paris Est, UPEC, CNRS, ICMPE UMR 7182, 2 Rue Henri Dunant, F-94320 Thiais, France

[2] Delft Univ Technol, Chem Engn, Delft, Netherlands

[3] Inst Energy Technol, N-2007 Kjeller, Norway

[4] Norwegian Univ Sci & Technol, N-7034 Trondheim, Norway

[5] Zentrum Mat & Kustenforsch GmbH, Helmholtz Zentrum Geesthacht, Geesthacht, Germany

[6] Univ Nottingham, Nottingham NG7 2RD, England

[7] Univ Quebec Trois Rivieres, Hydrogen Res Inst, Blvd Forges, Trois Rivieres, PQ 3351, Canada

[8] Aarhus Univ, Interdisciplinary Nanosci Ctr iNANO, Langelandsgade 140, DK-8000 Aarhus, Denmark

[9] Aarhus Univ, Dept Chem, Langelandsgade 140, DK-8000 Aarhus, Denmark

[10] Univ Utrecht, Debye Inst Nanomat Sci, Utrecht, Netherlands

[11] Univ Pavia, CSGI, Pavia Hydrogen Lab, Via Palestro 3, I-27100 Pavia, Italy

[12] Univ Pavia, Dept Chem, Via Palestro 3, I-27100 Pavia, Italy

[13] Lithuanian Energy Inst, Kaunas, Lithuania

[14] Griffith Univ, Queensland Micro & Nanotechnol Ctr, Brisbane, Qld 4111, Australia

来源：

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2016年 / 122卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

HYDROGEN STORAGE PROPERTIES; X-RAY-DIFFRACTION; MG-MM-NI; SORPTION KINETICS; ABSORPTION/DESORPTION PROPERTIES; NANOCRYSTALLINE MAGNESIUM; ABSORPTION PROPERTIES; CRYSTAL-STRUCTURE; BALL; SITU;

D O I：

10.1007/s00339-016-9602-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Magnesium hydride has been studied extensively for applications as a hydrogen storage material owing to the favourable cost and high gravimetric and volumetric hydrogen densities. However, its high enthalpy of decomposition necessitates high working temperatures for hydrogen desorption while the slow rates for some processes such as hydrogen diffusion through the bulk create challenges for large-scale implementation. The present paper reviews fundamentals of the Mg-H system and looks at the recent advances in the optimisation of magnesium hydride as a hydrogen storage material through the use of catalytic additives, incorporation of defects and an understanding of the rate-limiting processes during absorption and desorption.

引用

页码：1 / 20

页数：20

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