Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3-Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System

被引：4
作者：
Abbasi, Sepideh [1 ]
Reza Naimi-Jamal, Mohammad [1 ]
Javanshir, Shahrzad [2 ]
Heydari, Akbar [3 ]
机构：
[1] Iran Univ Sci & Technol IUST, Dept Chem, Res Lab Green Organ Synth & Polymers, Tehran 1684613114, Iran
[2] Iran Univ Sci & Technol, Chem Dept, Heterocycl Chem Res Lab, Tehran 1684613114, Iran
[3] Tarbiat Modares Univ, Chem Dept, Tehran 141554838, Iran
来源：
CHEMISTRYOPEN | 2022年 / 11卷 / 12期
关键词：
alcohol oxidation; deep eutectic solvent; green chemistry; heterogeneous catalyst; magnetic nanoparticles; FREE AEROBIC OXIDATION; METAL-FREE; MEDIA; ALDEHYDES; GREEN; DES;
D O I：
10.1002/open.202200172
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
K2CO3/Glycerin as a deep eutectic solvent (DES) was anchored covalently onto functionalized magnetic nanoparticles and showed a significant activity towards the oxidation of various alcohols under mild conditions with a short reaction time and good to high yield. A combination of the magnetic nanoparticles and deep eutectic solvent offers a novel, green, reusable catalyst with easy separation. Also, the catalyst structure was well characterized using techniques such as FT-IR spectroscopy, XRD, SEM, TGA, BET, VSM, TEM, and energy-dispersive X-ray spectroscopy (EDS).
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页数：9
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