Synthesis, structural characterization, and activity on the transfer hydrogenation reaction of dimesitylacetonate piano stool organometallic complexes of Ru(II), Rh(III), and Ir(III)

被引：3
作者：
Fernanda Ibarra-Vazquez, M. [1 ,4 ]
Alvarado-Rodriguez, Jose G. [2 ]
Esqueda, Ana C. [3 ]
Idalia Rangel-Salas, I. [1 ]
Serrano, Oracio [4 ]
机构：
[1] Univ Guadalajara, Ctr Univ Ciencias Exactas & Ingn, Dept Quim, Blvd Marcelino Garcia Barragan 1421, Guadalajara 44430, Jalisco, Mexico
[2] Univ Autonoma Estado Hidalgo, Unidad Univ, Km 4-5 Carretera Pachuca Tulancingo, Mineral De La Reforma 42184, Hidalgo, Mexico
[3] Univ Guanajuato, Escuela Nivel Medio Super Leon, Blvd Hermanos Aldama S-N, Leon 37000, Gto, Mexico
[4] Univ Guanajuato, Dept Quim, Sede Pueblito Rocha, Cerro La Velada S-N, Pueblito De Rocha 36040, Guanajuato, Mexico
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2019年 / 1191卷
基金：
芬兰科学院;
关键词：
Transfer hydrogenation reaction; Piano stool complexes; Microwave heating; Iridium; Rhodium; Ruthenium; ASYMMETRIC TRANSFER HYDROGENATION; CATALYTIC TRANSFER HYDROGENATION; LIGANDS; ACTIVATION; RHODIUM;
D O I：
10.1016/j.molstruc.2019.04.029
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new small family of Ru, Rh, and Ir piano-stool complexes partially containing the bulky acac(diMes), p-Cymene and Cp* ligands was synthetized and characterized. Their catalytic activity in transfer hydrogenation reaction was tested. The turn over frequency (TOF) values for aromatic- and alkyl-ketones giving the corresponding desired alcohols were increased in two orders of magnitude by using microwave heating compared with conventional thermal method. (C) 2019 Published by Elsevier B.V.
引用
收藏
页码：52 / 58
页数：7
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