Synthesis, structural characterization, and activity on the transfer hydrogenation reaction of dimesitylacetonate piano stool organometallic complexes of Ru(II), Rh(III), and Ir(III)

被引：3
|
作者：
Fernanda Ibarra-Vazquez, M. [1 ,4 ]
Alvarado-Rodriguez, Jose G. [2 ]
Esqueda, Ana C. [3 ]
Idalia Rangel-Salas, I. [1 ]
Serrano, Oracio [4 ]
机构：
[1] Univ Guadalajara, Ctr Univ Ciencias Exactas & Ingn, Dept Quim, Blvd Marcelino Garcia Barragan 1421, Guadalajara 44430, Jalisco, Mexico
[2] Univ Autonoma Estado Hidalgo, Unidad Univ, Km 4-5 Carretera Pachuca Tulancingo, Mineral De La Reforma 42184, Hidalgo, Mexico
[3] Univ Guanajuato, Escuela Nivel Medio Super Leon, Blvd Hermanos Aldama S-N, Leon 37000, Gto, Mexico
[4] Univ Guanajuato, Dept Quim, Sede Pueblito Rocha, Cerro La Velada S-N, Pueblito De Rocha 36040, Guanajuato, Mexico
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2019年 / 1191卷
基金：
芬兰科学院;
关键词：
Transfer hydrogenation reaction; Piano stool complexes; Microwave heating; Iridium; Rhodium; Ruthenium; ASYMMETRIC TRANSFER HYDROGENATION; CATALYTIC TRANSFER HYDROGENATION; LIGANDS; ACTIVATION; RHODIUM;
D O I：
10.1016/j.molstruc.2019.04.029
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new small family of Ru, Rh, and Ir piano-stool complexes partially containing the bulky acac(diMes), p-Cymene and Cp* ligands was synthetized and characterized. Their catalytic activity in transfer hydrogenation reaction was tested. The turn over frequency (TOF) values for aromatic- and alkyl-ketones giving the corresponding desired alcohols were increased in two orders of magnitude by using microwave heating compared with conventional thermal method. (C) 2019 Published by Elsevier B.V.
引用
收藏
页码：52 / 58
页数：7
相关论文
共 50 条
  • [1] Polynuclear Rh(III), Ir(III) and Ru(II) organometallic complexes: synthesis and biological evaluation as anticancer agents
    Burgoyne, Andrew R.
    Smith, Gregory S.
    Meyer, Mervin
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2014, 19 : S790 - S790
  • [2] Catalytic sugar-assisted transfer hydrogenation with Ru(II), Rh(III) and Ir(III) halfsandwich complexes
    Boege, Matthias
    Heck, Juergen
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2015, 408 : 107 - 122
  • [3] Synthesis and characterization of Ru(II), Rh(III) and Ir(III) complexes of the "Damphos" ligands and their application in the hydrogen transfer catalysis
    Totev, D
    Salzer, A
    Carmona, D
    Oro, LA
    Lahoz, FJ
    Dobrinovitch, IT
    INORGANICA CHIMICA ACTA, 2004, 357 (10) : 2889 - 2898
  • [4] Synthesis, characterization and catalytic activity of dinuclear half-sandwich Ru(II), Rh(III) and Ir(III) complexes
    Raja, Nandhagopal
    Therrien, Bruno
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 765 : 1 - 7
  • [5] SYNTHESIS AND CHARACTERIZATION OF RU(III), RH(III), PT(IV) AND IR(III) THIOSEMICARBAZONE COMPLEXES
    MUKKANTI, K
    SINGH, RP
    PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1988, 100 (01): : 21 - 26
  • [6] Experimental and DFT studies of sulfadiazine 'piano-stool' Ru(ii) and Rh(iii) complexes
    Mansour, Ahmed M.
    Radacki, Krzysztof
    RSC ADVANCES, 2020, 10 (18) : 10673 - 10680
  • [7] COMPLEXES OF ADENOSINE-TRIPHOSPHATE WITH RU(II), RU(III), RH(III) AND IR(III)
    KHAN, BT
    SOMAYAJULU, MR
    TAQUIKHAN, MM
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1979, 17 (04): : 359 - 360
  • [8] Synthesis, physicochemical characterization and antiproliferative activity of phosphino Ru(II) and Ir(III) complexes
    Komarnicka, Urszula K.
    Koziel, Sandra
    Skorska-Stania, Agnieszka
    Kyziol, Agnieszka
    Tisato, Francesco
    DALTON TRANSACTIONS, 2022, 51 (22) : 8605 - 8617
  • [9] Synthesis and evaluation of new polynuclear organometallic Ru(II), Rh(III) and Ir(III) pyridyl ester complexes as in vitro antiparasitic and antitumor agents
    Chellan, Prinessa
    Land, Kirkwood M.
    Shokar, Ajit
    Au, Aaron
    An, Seung Hwan
    Taylor, Dale
    Smith, Peter J.
    Riedel, Tina
    Dyson, Paul J.
    Chibale, Kelly
    Smith, Gregory S.
    DALTON TRANSACTIONS, 2014, 43 (02) : 513 - 526
  • [10] Synthesis, characterization, antiproliferative and molecular docking study of new half sandwich Ir(III), Rh(III) and Ru(II) complexes
    Thangavel, Saravanan
    Paulpandi, Manickam
    Friedrich, Holger B.
    Murugan, Kadarkarai
    Kalva, Sukesh
    Skelton, Adam A.
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2016, 159 : 50 - 61
12345