Ion-plus salinity gradient flow Battery

被引:8
|
作者
Jiang, Chenxiao [1 ,2 ]
Mei, Ying [1 ,4 ]
Chen, Binglun [2 ]
Li, Xianhui [1 ,5 ]
Yang, Zhe [1 ]
Guo, Hao [1 ]
Shao, Senlin [1 ]
Tan, Siew-Chong [3 ]
Xu, Tongwen [2 ]
Tang, Chuyang Y. [1 ]
机构
[1] Univ Hong Kong, Dept Civil Engn, Pokfulam Rd, Hong Kong, Peoples R China
[2] Univ Sci & Technol China, Collaborat Innovat Ctr Chem Energy Mat, Sch Chem & Mat Sci, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China
[3] Univ Hong Kong, Dept Elect & Elect Engn, Pokfulam Rd, Hong Kong, Peoples R China
[4] Beijing Normal Univ, Res & Dev Ctr Watershed Environm Ecoengn, Adv Inst Nat Sci, Zhuhai 519087, Peoples R China
[5] Guangdong Univ Technol, Inst Environm & Ecol Engn, Key Lab City Cluster Environm Safety & Green Dev, Minist Educ, Guangzhou 510006, Peoples R China
基金
中国国家自然科学基金;
关键词
Flow Battery; Salinity Gradient Power; Ion transfer; Energy-converting; Multiphysics simulation; ELECTROCHEMICAL ENERGY-STORAGE; PLANCK TRANSPORT-THEORY; REVERSE-ELECTRODIALYSIS; POWER-DENSITY; PRESSURE-DROP; PERFORMANCE; GENERATION; ELECTROLYTES; TECHNOLOGIES; TEMPERATURE;
D O I
10.1016/j.ces.2022.117580
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A Salinity Gradient Flow Battery (SGFB), as a novel energy-converting system, offered an alternative solution for the large-scale storage of renewable energy. Nevertheless, the commercialization of SGFB had been halted because the relatively high ohmic solution resistance in the low salinity solution. We proposed an "Ion-plus SGFB" system by internally-integrating the redox flow battery and SGFB system for the breakthrough of energy transforming efficiency in SGFB. The supporting ions in the salinity solutions overcome the trade-off limitation between Donnan potential and electrical-resistance as well as accelerate the ion transfer (mass transfer) without sacrificing on the SGP. The results suggest that 62.42-90.68% electric resistance was reduced, and the power density was more than doubled in the nonoptimized system. The novel designed system is environmental-friendly and gentle for membranes, and provided an effective option for the treatment of wastewater and the recovery of useful salinity gradient energy.(c) 2022 Elsevier Ltd. All rights reserved.
引用
收藏
页数:8
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