Thermal behaviour of the crystals formed in the Buckminsterfullerene-toluene, o-xylene and bromobenzene systems

被引：12

作者：

Avramenko, NV ^{[1
]}

Mirakyan, AL ^{[1
]}

Korobov, MV ^{[1
]}

机构：

[1] MOSCOW MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 119899,RUSSIA

来源：

THERMOCHIMICA ACTA | 1997年 / 299卷 / 1-2期

关键词：

DSC; fullerenes; incongruent melting; temperature dependence of solubility;

D O I：

10.1016/S0040-6031(97)00170-6

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Unusual solubility versus temperature dependence for C-60 fullerene in toluene and several other solvents is due to the formation of solid solvates. Temperature Maximum of Solubility (TMS) in toluene coincides with the incongruent melting point of the solvate with the mole ratio of C-60 to toluene 1 : 1.8 +/- 0.5. Similar results were obtained in the system C-60-bromobenzene, C-60-o-xylene, where solvates with the mole ratio 1 : 2 were found. Stoichiometry of the solvates of C-60 with the aromatic solvents are discussed in terms of incongruent melting.

引用

页码：141 / 144

页数：4

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