Magnetically Stabilized Bed for Selective Hydrogenation of Benzene

被引:5
作者
Yu, Lianqing [1 ]
Wang, Qingqing
Liu, Chenguang
Zhang, Yaping
Hao, Lanzhong
机构
[1] Shandong Univ, Coll Sci, China Univ Petr, Qingdao 266555, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
Benzene; Magnetic catalyst; Magnetically stabilized bed; Selective hydrogenation; FIELD ASSISTED FLUIDIZATION; UNIFIED APPROACH; CYCLOHEXENE; CATALYSTS; REACTOR;
D O I
10.1002/ceat.201300291
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The characteristics of a magnetically stabilized bed (MSB) were studied by cold-model experiments, using water as liquid phase, hydrogen as gas phase, and -Fe2O3 magnetic powder as solid phase. The fluidized state of different bed positions was investigated by testing the transmissible laser current. Effects of magnetic field intensity and gas flow rate on layer expansion states of the MSB were analyzed by color diagrams. A Ru-Zn-B amorphous alloy was prepared by chemical reduction. Selective hydrogenation of benzene was carried out in the MSB by adjusting the contact time between the catalysts and reactants through variations of reaction temperature, magnetic field current, and liquid hourly space velocity.
引用
收藏
页码:392 / 397
页数:6
相关论文
共 50 条
[21]   Purification of caprolactam in magnetically stabilized bed reactor [J].
Meng, XK ;
Mu, XH ;
Zong, BN ;
Min, E ;
Zhu, ZH ;
Fu, SB ;
Luo, YB .
CATALYSIS TODAY, 2003, 79 (1-4) :21-27
[22]   Continuously Conducted Selective Hydrogenation of Benzene to Cyclohexene in a Four-Phase System [J].
Spod, Hendrik ;
Lucas, Martin ;
Claus, Peter .
CHEMICAL ENGINEERING & TECHNOLOGY, 2015, 38 (08) :1340-1342
[23]   Continuously Conducted Selective Hydrogenation of Benzene to Cyclohexene in a Four-Phase System [J].
Spod, Hendrik ;
Lucas, Martin ;
Claus, Peter .
CHEMIE INGENIEUR TECHNIK, 2015, 87 (05) :559-562
[24]   Ruthenium-Catalyzed Selective Hydrogenation of Benzene to Cyclohexene in the Presence of an Ionic Liquid [J].
Schwab, Frederick ;
Lucas, Martin ;
Claus, Peter .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (44) :10453-10456
[25]   Selective hydrogenation of benzene to cyclohexene over Ce-promoted Ru catalysts [J].
Haijie Sun ;
Yajie Pan ;
Shuaihui Li ;
Yuanxin Zhang ;
Yingying Dong ;
Shouchang Liu ;
Zhongyi Liu .
Journal of Energy Chemistry, 2013, 22 (05) :710-716
[26]   Selective hydrogenation of benzene to cyclohexene over Ce-promoted Ru catalysts [J].
Sun, Haijie ;
Pan, Yajie ;
Li, Shuaihui ;
Zhang, Yuanxin ;
Dong, Yingying ;
Liu, Shouchang ;
Liu, Zhongyi .
JOURNAL OF ENERGY CHEMISTRY, 2013, 22 (05) :710-716
[27]   Selective hydrogenation of acetone in the presence of benzene [J].
Shutkina, O. V. ;
Ponomareva, O. A. ;
Kots, P. A. ;
Ivanova, I. I. .
CATALYSIS TODAY, 2013, 218 :30-34
[28]   Axial liquid dispersion characteristics in magnetically stabilized bed [J].
Zhang Dongli ;
Zhang Yanjun ;
Zhang Jinli ;
Li Xiaofang ;
Lu Lixiang ;
Meng Xiangkun ;
Mu Xuhong .
CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2006, 14 (04) :532-536
[29]   Axial Liquid Dispersion Characteristics in Magnetically Stabilized Bed [J].
张东利 ;
张艳君 ;
张金利 ;
李晓芳 ;
卢立祥 ;
孟祥坤 ;
慕旭宏 .
ChineseJournalofChemicalEngineering, 2006, (04) :532-536
[30]   Selective hydrogenation of benzene to cyclohexene on Ru-based catalysts promoted with Mn and Zn [J].
Xiaoli Zhou Haijie Sun Wei Guo Zhongyi Liu Shouchang Liu Department of Chemistry Zhengzhou University Zhengzhou Henan China .
Journal of Natural Gas Chemistry, 2011, 20 (01) :53-59