LARGE COERCIVITY IN ANTIFERROMAGNETIC Mn2O3/Mn5O8 AND MnO/Mn NANOPARTICLES

被引:4
作者
Si, P. Z. [1 ,2 ]
Zhang, Z. D. [1 ,3 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
[2] China Jiliang Univ, Dept Mat Sci & Engn, Hangzhou 310018, Peoples R China
[3] Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
来源
INTERNATIONAL JOURNAL OF MODERN PHYSICS B | 2009年 / 23卷 / 19期
基金
中国国家自然科学基金; 浙江省自然科学基金;
关键词
Manganese oxide; nanoparticles; magnetic properties; ANOMALOUS MAGNETIC-PROPERTIES; CR2O3; NANOPARTICLES; MN3O4; COO; NIO;
D O I
10.1142/S0217979209052984
中图分类号
O59 [应用物理学];
学科分类号
摘要
Mn2O3/Mn5O8 and MnO/Mn nanoparticles were prepared by annealing manganese nanoparticles in air and hydrogen, respectively. The antiferromagnetic Mn2O3/Mn5O8 and MnO/Mn nanoparticles exhibit anomalous magnetic properties, such as large moments, and large coercivity of up to 169 kA/m and 105 kA/m, respectively. This ferromagnetic-like behavior is attributed to the finite size effect of antiferromagnetic nanoparticles and the presence of ferrimagnetic Mn3O4 phases.
引用
收藏
页码:3693 / 3699
页数:7
相关论文
共 20 条
  • [1] Fabrication and abnormal magnetic properties of MnO nanoparticles via vapor phase growth
    Chang, YQ
    Yu, DP
    Wang, Z
    Long, Y
    Zhang, HZ
    Ye, RC
    [J]. JOURNAL OF CRYSTAL GROWTH, 2005, 281 (2-4) : 678 - 682
  • [2] Synthesis of nanocrystalline Mn-oxides by gas condensation
    Dimesso, L
    Heider, L
    Hahn, H
    [J]. SOLID STATE IONICS, 1999, 123 (1-4) : 39 - 46
  • [3] Low-temperature oxidation of Mn3O4 hausmannite
    Fritsch, S
    Sarrias, J
    Rousset, A
    Kulkarni, GU
    [J]. MATERIALS RESEARCH BULLETIN, 1998, 33 (08) : 1185 - 1194
  • [4] STUDY OF SOME MAGNETIC-PROPERTIES OF A MIXED PHASE (MN3O4) IN MNO CRYSTALS
    JAGADEESH, MS
    SEEHRA, MS
    [J]. PHYSICAL REVIEW B, 1980, 21 (07): : 2897 - 2904
  • [5] ANTIFERROMAGNETIC STRUCTURE OF ALPHA-MANGANESE AND A MAGNETIC STRUCTURE STUDY OF BETA-MANGANESE
    KASPER, JS
    ROBERTS, BW
    [J]. PHYSICAL REVIEW, 1956, 101 (02): : 537 - 544
  • [6] Finite size effects in antiferromagnetic NiO nanoparticles
    Kodama, RH
    Makhlouf, SA
    Berkowitz, AE
    [J]. PHYSICAL REVIEW LETTERS, 1997, 79 (07) : 1393 - 1396
  • [7] Anomalous magnetic properties of MnO nanoclusters
    Lee, GH
    Huh, SH
    Jeong, JW
    Choi, BJ
    Kim, SH
    Ri, HC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (41) : 12094 - 12095
  • [8] The enhanced magnetic properties of Ni nanocrystallites induced by the coupling between Ni/NiO interfaces
    Li, Shandong
    Liu, Meimei
    Bi, Hong
    Lu, Liya
    Zou, Wenqin
    Huang, Zhigao
    Du, Youwei
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 425 (1-2) : 1 - 3
  • [9] Magnetic properties of Cr2O3 nanoparticles
    Makhlouf, SA
    [J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2004, 272 : 1530 - 1532
  • [10] Ferromagnetism of MnO and Mn3O4 nanowires -: art. no. 142504
    Na, CW
    Han, DS
    Kim, DS
    Park, J
    Jeon, YT
    Lee, G
    Jung, MH
    [J]. APPLIED PHYSICS LETTERS, 2005, 87 (14) : 1 - 3