Synthesis and Properties of Poly (p-phenylene vinylene) with Carbazole in the Side Chain

被引:1
作者
Ikeda, Koichi [1 ]
Kouzai, Hiroaki [1 ]
机构
[1] Kanto Gakuin Univ, Coll Engn, Dept Appl Mat & Life Sci, Kanazawa Ku, Yokohama, Kanagawa 2368501, Japan
关键词
Carbazole; Poly (p-phenylenevinylene); Luminescence; Photo-Functional Material; CONJUGATED POLYMER; ELECTROLUMINESCENCE; PPV;
D O I
10.1295/koron.66.230
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We synthesized PPV with carbazole in the side chain, and we examined the polymer's characteristics. Our purpose was improved the luminescence properties of PPV when used as a luminescence material. The number-average molecular weight and the weight-average molecular weight of the polymer, determined by GPC using a polystyrene standard, were 5.5 x 10(3) and 6.0 x 10(3), respectively. The synthesized polymer showed photoluminescence peaks at 380 and 480 nm. Further, from the TGA measurements of polymer, showed that the polymer had a 10% thermal weight loss initiation temperature of 345 degrees C.
引用
收藏
页码:230 / 233
页数:4
相关论文
共 6 条
  • [1] Blue electroluminescent polymers:: Control of conjugation length by kink linkages and substituents in the poly(p-phenylenevinylene)-related copolymers
    Ahn, T
    Jang, MS
    Shim, HK
    Hwang, DH
    Zyung, T
    [J]. MACROMOLECULES, 1999, 32 (10) : 3279 - 3285
  • [2] Solvent and molecular weight effects on fluorescence emission of MEH-PPV
    Cossiello, RF
    Akcelrud, L
    Atvars, DZ
    [J]. JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2005, 16 (01) : 74 - 86
  • [3] A novel soluble poly(fluorenylenevinylene) conjugated polymer:: synthesis, characterization and application to optoelectronic devices
    Gruber, J
    Li, RWC
    Aguiar, LHJMC
    Benvenho, ARV
    Lessmann, R
    Hümmelgen, IA
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (04) : 517 - 522
  • [4] Synthesis and characterization of poly(2,5-bis(N-methyl-N-hexylamino)phenylene vinylene), a conjugated polymer for light-emitting diodes
    Stenger-Smith, JD
    Zarras, P
    Merwin, LH
    Shaheen, SE
    Kippelen, B
    Peyghambarian, N
    [J]. MACROMOLECULES, 1998, 31 (21) : 7566 - 7569
  • [5] Halogen precursor route to poly[(2,3-diphenyl-p-phenylene)vinylene] (DP-PPV): Synthesis, photoluminescence, electroluminescence, and photoconductivity
    Wan, WC
    Antoniadis, H
    Choong, VE
    Razafitrimo, H
    Gao, Y
    Feld, WA
    Hsieh, BR
    [J]. MACROMOLECULES, 1997, 30 (21) : 6567 - 6574
  • [6] Synthesis of laterally attached side-chain liquid crystalline poly(p-phenylene vinylene) and polyfluorene derivatives for the application of polarized electroluminescence
    Yao, Yung-Hsin
    Yang, Sheng-Hsiung
    Hsu, Chain-Shu
    [J]. POLYMER, 2006, 47 (25) : 8297 - 8308