Ni and Ga diffusion in polycrystalline Ni3Ga

被引:8
作者
Cermák, J [1 ]
Rothová, V [1 ]
机构
[1] Inst Phys & Mat, AS CR, CZ-61662 Brno, Czech Republic
关键词
intermetallics; miscellaneous; diffusion;
D O I
10.1016/S0966-9795(02)00053-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The volume and grain boundary (GB) diffusion of Ni-63 and Ga-67 radiotracers in polycrystals of Ni3Ga intermetallic was studied in the vicinity of the stoichiometric composition A(3)B (23.5-28.3 at.% Ga). Both volume and GB diffusivity was investigated in the temperature interval 773-1373 K by the residual activity method. The obtained Ga volume diffusivity increases with increasing Ga concentration x(Ga;) the increasing tendency of Ni volume diffusivity with increasing x(Ga) is pronounced at lower temperatures. GB diffusivity of both Ga and Ni in Ni3Ga are close one to another and-contrary to the diffusion behavior of components in Ni3Al-they do not show any significant dependence on x(Ga). (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:765 / 769
页数:5
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