Highly efficient blue-green delayed fluorescence from copper(I) thiolate complexes: luminescence color alteration by orientation change of the aryl ring

被引:113
作者
Osawa, Masahisa [1 ]
机构
[1] RIKEN, Mol Spect Lab, Wako, Saitama 3510198, Japan
关键词
LIGHT-EMITTING-DIODES; PHOTOPHYSICAL PROPERTIES; DEVICES; LIGANDS; SINGLET; DESIGN; OLEDS;
D O I
10.1039/c3cc47871h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly emissive three-coordinate thiolate copper(I) complexes are synthesized and characterized. The Cu(I) complexes emit intense blue-green delayed fluorescence with high photoluminescence quantum yields of approximately 1.0 at both 293 K and 77 K in the solid state, whereas orange emission at 293 K in solution is observed.
引用
收藏
页码:1801 / 1803
页数:3
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