Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

被引:12
作者
Faust, Thomas B. [1 ]
Usov, Pavel M. [1 ]
D'Alessandro, Deanna M. [1 ]
Kepert, Cameron J. [1 ]
机构
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
基金
澳大利亚研究理事会;
关键词
METAL-ORGANIC FRAMEWORKS; COMPLEXES;
D O I
10.1039/c4cc05438e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The metalloligand [Ni(pedt)(2)](-) (pedt = 1-(pyridine-4-yl)ethylene-1,2-dithiolate) has been incorporated into two multi-dimensional structures for the first time. These coordination frameworks represent highly unusual interpenetration isomers and exhibit solid state redox and optical properties that reflect the electronically delocalised nature of the metalloligand.
引用
收藏
页码:12772 / 12774
页数:3
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