Hexakis(silyl)palladium(VI) or palladium(II) with η2-disilane ligands?

被引:0
作者
Aullón, G
Lledós, A
Alvarez, S
机构
[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
[2] Univ Barcelona, Ctr Recerca Quim Teor, E-08028 Barcelona, Spain
[3] Univ Autonoma Barcelona, Dept Quim, Bellaterra 08193, Spain
关键词
agostic interactions; density functional calculations; electronic structure; palladium; Si ligands;
D O I
10.1002/1521-3773(20020603)41:11<1956::AID-ANIE1956>3.0.CO;2-#
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Side-bound Si-Si single bonds: A theoretical study indicates that in a recently reported compound, two Si-Si bonds are side-on coordinated to a square-planar PdII ion (see picture).
引用
收藏
页码:1956 / +
页数:5
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