The preparation of polymer beads by photocationic suspension co-polymerisation of 2-(arylsilyl)ethyl vinyl ethers

被引：4

作者：

Porres, L ^{[1
]}

Deleuze, H ^{[1
]}

Landais, Y ^{[1
]}

机构：

[1] Univ Bordeaux 1, Chim Organ & Organomet Lab, CNRS, UMR 5802, F-33405 Talence, France

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2002年 / 19期

关键词：

D O I：

10.1039/b201520j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polymer beads have been prepared by photocationic suspension polymerisation of 2-(aryldimethyl)silyl ethers in perfluorooctane in the course of our studies on polymer-supported desymmetrisation of 1-silacyclohexa-2,5-dienes. Good yields of 100-200 mum beads of satisfactory shape have been obtained using a perfluorinated co-polymer as stabilising agent. These beads have no permanent porosity although they have a high nominal cross-linking level. Their swelling in common organic solvents is comparable with those of Merrifield or TentaGel gel-type resins.

引用

页码：2198 / 2203

页数：6

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