Controllable synthesis of porous LiFePO4 for tunable electrochemical Li-insertion performance

被引：33

作者：

Tian, Xiaohui ^{[1
]}

Zhou, Yingke ^{[1
]}

Wu, Guan ^{[1
]}

Wang, Pengcheng ^{[1
]}

Chen, Jian ^{[1
]}

机构：

[1] Wuhan Univ Sci & Technol, State Key Lab Refractories & Met, Coll Mat & Met, Wuhan 430081, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2017年 / 229卷

基金：

中国国家自然科学基金;

关键词：

Porous LiFePO4; Template synthesis; Freeze-drying; Lithium-ion batteries; CATHODE MATERIAL; CARBON NANOTUBES; MESOPOROUS LIFEPO4; ION; COMPOSITE; MICROSPHERES; BATTERY;

D O I：

10.1016/j.electacta.2017.01.093

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A templated freeze-drying method is developed to prepare the porous LiFePO4 materials with the controlled pore size and porosity, by conveniently adjusting the size and content of the template in the precursor solution. The morphology and structure of the porous LiFePO4 materials are characterized and the relavant electrochemical lithium-insertion performances are systematically studied. It's found that the porous characteristics play a critical role in the lithium-ion intercalation processes and significantly affect the power capability of LiFePO4. The optimized porous LiFePO4 material presents remarkable specific capacity (167 mAh g(-1) at 0.1 C), rate capability (151 mAh g(-1) at 1 C and 110 mAhg(-1) at 10 C) and cycling stability (99.3% retention after 300 cycles at 1 C). These findings demonstrate that the electrochemical performance of the electrode material can be purposely tuned and remarkably improved by the rational design and introduction of the suitable pores, which open up new strategies for the synthesis of advanced porous materials for the lithium-ion power battery applications. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：316 / 324

页数：9

共 33 条

[1] Porous Electrode Materials for Lithium-Ion Batteries - How to Prepare Them and What Makes Them Special [J].