Hydrolysis Kinetics of Chloroacetic Acid with Sodium Hydroxide Under Strong Alkaline Conditions

被引：5
|
作者：
Li, Wenze [1 ,2 ]
Chang, Shaoqing [2 ]
Chen, Xin [2 ]
Qi, Xuan [2 ]
Sun, Hong-Bin [2 ]
机构：
[1] Shenyang Univ Chem Technol, Coll Appl Chem, Shenyang 110142, Peoples R China
[2] Northeastern Univ, Coll Sci, Shenyang 110819, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2014年 / 26卷 / 11期
基金：
中国国家自然科学基金;
关键词：
Hydrolytic kinetic; Chloroacetic acid; Hydrolysis; Reaction rate coefficient;
D O I：
10.14233/ajchem.2014.17537
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrolysis of chloroacetic acid and sodium hydroxide is carried out at 45-85 degrees C by using equal mole of sodium chloroacetate and alkali. Using reasonable approximation, the hydrolysis reaction is proved to be a second-order reaction when the conversion is less than 95 % and the kinetic rate coefficients are determined. The activate energy is calculated 103 kJ mol(-1).
引用
收藏
页码：3404 / 3406
页数：3
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