Ordered Mesoporous Carbide Derived Carbons: Novel Materials for Catalysis and Adsorption

被引：91
作者：
Krawiec, Piotr [1 ]
Kockrick, Emanuel [2 ]
Borchardt, Lars [2 ]
Geiger, Dorin [3 ]
Corma, Avelino [1 ]
Kaskel, Stefan [2 ]
机构：
[1] UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[2] Tech Univ Dresden, Dept Inorgan Chem, D-01062 Dresden, Germany
[3] Tech Univ Dresden, Inst Struct Phys, Triebenberg Lab HRTEM & Electron Holog, D-01328 Dresden, Germany
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 18期
关键词：
METAL-ORGANIC FRAMEWORK; SILICON-CARBIDE; HYDROGEN-STORAGE; CARBONACEOUS MATERIALS; NANOPOROUS CARBON; POROUS MATERIALS; PORE-SIZE; SURFACE; POROSITY; TRANSFORMATION;
D O I：
10.1021/jp808470s
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
New ordered mesoporous carbide derived carbon materials with extraordinary high specific surface areas up to similar to 2800 m(2) g(-1) were synthesized by selective extraction of silicon from ordered mesoporous silicon carbide. Although the degree of mesostructure ordering is lower than that of the CMK-type materials they exhibit higher specific surface areas and high protein adsorption capacities. We show that they can be effectively functionalized with sulfonic groups and become excellent solid acid catalysts for processing large organic molecules.
引用
收藏
页码：7755 / 7761
页数：7
相关论文
共 48 条
[1]   Surface and pore structure modification of ordered mesoporous carbons via a chemical oxidation approach [J].
Bazula, Piotr A. ;
Lu, An-Hui ;
Nitz, Joerg-Joachim ;
Schueth, Ferdi .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 108 (1-3) :266-275
[2]   Starbons: New starch-derived mesoporous carbonaceous materials with tunable properties [J].
Budarin, Vitaly ;
Clark, James H. ;
Hardy, Jeffrey J. E. ;
Luque, Rafael ;
Milkowski, Krzysztof ;
Tavener, Stewart J. ;
Wilson, Ashley J. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (23) :3782-3786
[3]   Tunable mesoporous materials optimised for aqueous phase esterifications [J].
Budarin, Vitaly L. ;
Clark, James H. ;
Luque, Rafael ;
Macquarrie, Duncan J. ;
Koutinas, Apostolis ;
Webb, Colin .
GREEN CHEMISTRY, 2007, 9 (09) :992-995
[4]   Versatile mesoporous carbonaceous materials for acid catalysis [J].
Budarin, Vitaly L. ;
Clark, James H. ;
Luque, Rafael ;
Macquarrie, Duncan J. .
CHEMICAL COMMUNICATIONS, 2007, (06) :634-636
[5]  
Chmiola J, 2006, SCIENCE, V313, P1760, DOI [10.1126/science.1132195, 10.1126/science/1132195]
[6]   Desolvation of ions in subnanometer pores and its effect on capacitance and double-layer theory [J].
Chmiola, John ;
Largeot, Celine ;
Taberna, Pierre-Louis ;
Simon, Patrice ;
Gogotsi, Yury .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) :3392-3395
[7]   Facile synthesis of high quality mesoporous SBA-15 with enhanced control of the porous network connectivity and wall thickness [J].
Choi, M ;
Heo, W ;
Kleitz, F ;
Ryoo, R .
CHEMICAL COMMUNICATIONS, 2003, (12) :1340-1341
[8]   From microporous to mesoporous molecular sieve materials and their use in catalysis [J].
Corma, A .
CHEMICAL REVIEWS, 1997, 97 (06) :2373-2419
[9]   Titanium carbide derived nanoporous carbon for energy-related applications [J].
Dash, Ranjan ;
Chmiola, John ;
Yushin, Gleb ;
Gogotsi, Yury ;
Laudisio, Giovanna ;
Singer, Jonathan ;
Fischer, John ;
Kucheyev, Sergei .
CARBON, 2006, 44 (12) :2489-2497
[10]   Synthesis, structure and porosity analysis of microporous mesoporous carbon derived from zirconium carbide [J].
Dash, RK ;
Yushin, G ;
Gogotsi, Y .
MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 86 (1-3) :50-57
12345