Highly selective multifunctional nanohybrid catalysts for the one-pot synthesis of α,β-epoxy-chalcones

被引：11

作者：

Crivoi, Dana-Georgiana

Segarra, Anna M. ^{[1
]}

Medina, Francesc ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Dept Engn Quim, Ave Paisos Catalans,26,Campus Sescelades, E-43007 Tarragona, Spain

来源：

JOURNAL OF CATALYSIS | 2016年 / 334卷

关键词：

One-pot reaction; Asymmetric catalysis; Nanohybrid; Poly-L-leucine; Hydrotalcite; Chiral alpha; beta-epoxy-chalcone; CLAISEN-SCHMIDT CONDENSATION; POLY-L-LEUCINE; SOLID BASE CATALYSTS; ASYMMETRIC EPOXIDATION; ALDOL CONDENSATION; ENANTIOSELECTIVE EPOXIDATION; ACTIVATED HYDROTALCITES; PHARMACEUTICAL INTEREST; POLYAMINO-ACIDS; IONIC LIQUID;

D O I：

10.1016/j.jcat.2015.11.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An efficient one-pot heterogeneous process for producing chiral alpha,beta-epoxy-chalcones from the corresponding aldehydes and ketones, has been described. The nanohybrid materials based on poly-L-leucine immobilised into rehydrated hydrotalcites did not require any pre-activation and were easily recovered and recycled for four consecutive runs without losing their catalytic efficiency in terms of conversion, total selectivity towards the corresponding epoxy-chalcones and excellent enantioselectivity. (C) 2015 Elsevier Inc. All rights reserved.

引用

页码：120 / 128

页数：9

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