{[M(NH3)6][Ag4M4Sn3Se13]}∞ (M=Zn, Mn): Three-dimensional chalcogenide frameworks constructed from quaternary metal selenide clusters with two different transition metals

被引：18

作者：

Xiong, Wei-Wei ^{[1
]}

Miao, Jianwei ^{[2
]}

Li, Pei-Zhou ^{[3
]}

Zhao, Yanli ^{[3
]}

Liu, Bin ^{[2
]}

Zhang, Qichun ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore

[3] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2014年 / 218卷

关键词：

Chalcogenides; Quaternary; Clusters; Photoactive; Photoelectrochemical cell; IONIC LIQUIDS; SULFIDE; SEMICONDUCTOR; CHEMISTRY; TERNARY; ORGANIZATION; SYNTHESIZE; CATION;

D O I：

10.1016/j.jssc.2014.06.035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein we report solvothermal syntheses of two new three-dimensional chalcogenide frameworks {[M (NH3)(6)][Ag4M4Sn3Se13]}(n) (M=Zn (1), Mn (2)), which consist of quaternary metal selenide clusters with two different transition metals. The compounds represent the first Ag-Zn/Mn-Sn-Se based quaternary anionic frameworks. The optical studies show that the band gaps for 1 and 2 are 2.09 eV and 1.71 eV, respectively. Moreover, the photoelectrochemical study indicates that compound I displays n-type semiconducting behaviour and is photoactive under visible light illumination (lambda > 400 nm). (C) 2014 Elsevier Inc. All rights reserved.

引用

页码：146 / 150

页数：5