Evaluation and optimization of a novel geothermal-driven hydrogen production system using an electrolyser fed by a two-stage organic Rankine cycle with different working fluids

In this study, a novel system comprising of a two-stage organic Rankine cycle, driven by geothermal energy and coupled with a proton exchange membrane electrolyser, is investigated and optimized from thermodynamic and exergoeconomic viewpoints. Various working fluids are considered so as to ascertain the effects of thermo-physical properties on the performance of the system. The electricity output from the two-stage organic Rankine cycle is employed to produce hydrogen through electrochemical reactions in the proton exchange membrane electrolyser. The effects are assessed on key parameters of variations in geothermal water temperature and the pressure ratio of high-pressure organic Rankine cycle turbine. Considering three distinct cases, a thorough optimization is performed utilizing a genetic algorithm. It is concluded that a 2-3 percent-point improvement in energy efficiency, as well as a 35% to 41% increase in hydrogen production and a 9.5% to 12% reduction in cost per unit exergy of hydrogen can be achieved via optimization. R123 is shown in the optimization to perform the best among the considered working fluids, with isopentane performing second best.