A tetrahedral coordination cage based on p-tert-butylthiacalix[4]arene and 5-sulfoisophthalic acid

被引：17
作者：
Liu, Mei [1 ,2 ]
Du, Shangchao [1 ,2 ]
Bi, Yanfeng [1 ]
Liao, Wuping [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, ERC Separat & Purificat REs & Thorium, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 41卷
基金：
中国国家自然科学基金;
关键词：
Cage compounds; Calixarenes; Cobalt; Crystal engineering; Magnetic property; CO-4-TC4A SUBUNITS;
D O I：
10.1016/j.inoche.2014.01.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new cobalt-thiacalix[4]arene compound [(CH3)(4)N](2) {[Co4Cl(TC4A)(CH3OH)](4)(SIP)(4)(HCOO)(2)} (CIAC-111) was synthesized by the solvothermal reaction of CoCl2 center dot 6H(2)O, p-tert-butylthiacalix[4]arene (H(4)TC4A) and 5-sulfoisophthalic acid sodium salt (NaH2SIP). It is featured with a tetrahedral coordination cage with four Co-4-TC4A shuttlecock-like subunits as the vertices and four SIP molecules as the tripod linkers located on the triangular faces. The structure and coordination mode of SIP play a crucial role in the formation of such a cage. The magnetic property of this compound was examined. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：96 / 99
页数：4
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