A glycyl-substituted porphyrin as a starting compound for the synthesis of a π-π-stacked porphyrin-fullerene dyad with a frozen geometry

被引：12

作者：

Lembo, Angelo ^{[1
]}

Tagliatesta, Pietro ^{[1
]}

Cicero, Daniel ^{[1
]}

Leoni, Alessandro ^{[1
]}

Salvatori, Alisa ^{[1
]}

机构：

[1] Univ Roma Tor Vergata, Dipartimetno Sci & Tecnol Chim, I-00133 Rome, Italy

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2009年 / 7卷 / 06期

关键词：

PHOTOINDUCED ELECTRON-TRANSFER; CHARGE-TRANSFER INTERACTIONS; ELECTROCHEMICAL PROPERTIES; PHOTOSYNTHETIC ANTENNA; AZOMETHINE YLIDES; INVERTED REGION; SOLAR-ENERGY; DESIGN; SYSTEMS; FULLEROPYRROLIDINES;

D O I：

10.1039/b820501a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthetic route for obtaining a porphyrin-fullerene dyad with a constrained geometry forcing the [60] fullerene sphere to lie on the porphyrin plane is reported, revealing a strong interaction in the ground state between the two chromophores.

引用

页码：1093 / 1096

页数：4

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