Mild and efficient method for the synthesis of nitriles

被引:11
作者
Coskun, N [1 ]
机构
[1] Uludag Univ, Dept Chem, TR-16059 Gorukle, Bursa, Turkey
关键词
nitriles; hydrazine; DMAD; oximes;
D O I
10.1081/SCC-120030750
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The treatment of aldoximes with a mixture of DMAD and triethylamine serve as an efficient and mild method for the synthesis of aromatic and alpha,beta-unsaturated nitriles in high yields at room temperature.
引用
收藏
页码:1625 / 1630
页数:6
相关论文
共 7 条
[1]   High-yield synthesis of nitriles by oxidation of aldehyde N,N-dimethylhydrazones with dimethyldioxirane [J].
Altamura, A ;
D'Accolti, L ;
Detomaso, A ;
Dinoi, A ;
Fiorentino, M ;
Fusco, C ;
Curci, R .
TETRAHEDRON LETTERS, 1998, 39 (14) :2009-2012
[2]  
BARTON D, 1979, COMPREHENSIVE ORGANI, V2, P532
[3]   A clean conversion of aldehydes to nitriles using a solid-supported hydrazine [J].
Baxendale, IR ;
Ley, SV ;
Sneddon, HF .
SYNLETT, 2002, (05) :775-777
[4]   Direct conversion of aldehydes into nitriles via O-phenylcarbamoylated aldoximes [J].
Coskun, N ;
Arikan, N .
TETRAHEDRON, 1999, 55 (40) :11943-11948
[5]   Reactivity of bis(arylcarbamoyl)-N-arylphenacylamine oximes.: Synthesis of 1,3-dihydroimidazol-2-ones and N-unsubstituted O-arylcarbamoylhydroxylamines [J].
Coskun, N .
TETRAHEDRON, 1999, 55 (02) :475-484
[6]  
MARCH J, 1985, ADV ORG CHEM, P806
[7]   Transfer factors of 90Sr and 137Cs from paddy soil to the rice plant in Taiwan [J].
Wang, JJ ;
Wang, CJ ;
Huang, CC ;
Lin, YM .
JOURNAL OF ENVIRONMENTAL RADIOACTIVITY, 1998, 39 (01) :23-34