Bis{(μ-nitrato)[μ-bis(salicylidene)-1,3-propanediaminato] copper(II)}zinc(II)

被引：18

作者：

Ülkü, D ^{[1
]}

Tatar, L

Atakol, O

Durmus, S

机构：

[1] Hacettepe Univ, Dept Engn Phys, TR-06532 Ankara, Turkey

[2] Ankara Univ, Dept Chem, TR-06100 Ankara, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199008513

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Zn{Cu(NO3)(C17H16N2O2)}(2)], has the central Zn2+ ion located on an inversion centre, with four bridging O atoms from two N,N'-bis(salicylidene)-1,3-propanediaminate (SALPD(2-)) ligands and one O atom from each bridging nitrate group as nearest neighbours. This arrangement constitutes a distorted octahedral coordination around the Zn2+ ion. The inversion-related terminal Cu2+ ions have irregular square-pyramidal coordinations involving two. O and two N atoms of a SALPD(2-) ligand and one O atom from a nitrate group in the axial position. The Zn-Cu pairs are triple bridged by the SALPD(2-) O atoms and by the O-N-O atoms of the nitrate groups. The Zn Cu bridging distance is 3.0017 (6) Angstrom.

引用

页码：1652 / 1654

页数：3

共 10 条

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