Wet air co-oxidation of decabromodiphenyl ether (BDE209) and tetrahydrofuran

被引：13

作者：

Zhao, Hongxia ^{[1
,2
]}

Zhang, Feifang ^{[1
]}

Qu, Baocheng ^{[2
]}

Xue, Xingya ^{[1
]}

Liang, Xinmiao ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

[2] Dalian Univ Technol, Key Lab Ind Ecol & Environm Engn, MOE, Dalian 116024, Peoples R China

来源：

JOURNAL OF HAZARDOUS MATERIALS | 2009年 / 169卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

Co-oxidation; BDE209; THF; Promotion effect; Free radical; POLYBROMINATED DIPHENYL ETHERS; BROMINATED FLAME RETARDANTS; REDUCTIVE DEBROMINATION; OXIDATION;

D O I：

10.1016/j.jhazmat.2009.03.089

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The wet air co-oxidation (WACO) of a major commercial polybrominated diphenyl ether flame retardant congener, decabromodiphenyl ether (BDE209), was investigated using tetrahydrofuran (THF) as an initiator in a stainless autoclave at temperature range of 120-170 degrees C and 0.5 MPa oxygen pressure. Compared to the single oxidation of BDE209 under the same conditions, the addition of THF in the reaction system greatly improved the removal efficiency of BDE209. The effect of temperature on the reaction was studied. The removals of BDE209 and Br increased with increasing temperature. In addition, the effect of NaNO2 as the catalyst on the WACO was also investigated and the results showed that the addition of NaNO2 could improve the Br removal efficiency. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1146 / 1149

页数：4

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