Applications of Pybox Complexes in Asymmetric Catalysis

被引：37
作者：
Babu, Sheba Ann [1 ]
Krishnan, K. Keerthi [1 ]
Ujwaldev, S. M. [1 ]
Anilkumar, Gopinathan [1 ]
机构：
[1] Mahatma Gandhi Univ, Sch Chem Sci, Priyadarsini Hills, Kottayam 686560, Kerala, India
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 06期
关键词：
asymmetric synthesis; C-C bond formation; heteroatoms; Pybox; stereoselectivity; FRIEDEL-CRAFTS ALKYLATION; CROSS-COUPLING REACTIONS; CARBONYL-ENE REACTIONS; C-H BONDS; ALDOL REACTION; ENANTIOSELECTIVE SYNTHESIS; IN(III)-PYBOX COMPLEX; TERMINAL ALKYNES; MUKAIYAMA ALDOL; PYBOX-DIPH-ZN(II) COMPLEX;
D O I：
10.1002/ajoc.201800094
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Pybox ligands have found widespread application in organic synthesis and catalysis ever since their discovery, and their involvement in various C-C and C-heteroatom bond-forming reactions is rapidly increasing. In this Focus Review, we summarise the reactions involving various Pybox-metal combinations used for forming C-C bonds, such as cross-coupling reactions, carbonyl-ene reactions, three-component reactions, allylation reactions, Diels-Alder reactions and other C-C bond-forming reactions. The literature from 2006 to 2017 is covered.
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页码：1033 / 1053
页数：21
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