Covalent exchange vs superexchange in two nickel oxides

被引：35

作者：

Goodenough, JB

机构：

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1996年 / 127卷 / 01期

关键词：

D O I：

10.1006/jssc.1996.0366

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It is pointed out that the peculiar antiferromagnetic order found in NdNiO3 and the ferromagnetic coupling of the Ni2+ in the Li layers of Li1-xNi1+xO2, x less than or equal to 0.08, to the ferromagnetic NiO2 sheets can be accounted for by a shift of the Ni3+-O2-=Ni2+-O- equilibrium to the right, which introduces a magnetic coupling carrying the sign of covalent exchange rather than superexchange. (C) 1996 Academic Press, Inc.

引用

页码：126 / 127

页数：2

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