[Cd{C2(COO)2}(H2O)3]•H2O, the first cadmium salt of acetylenedicarboxylic acid

被引：23
|
作者：
Ruschewitz, U [1 ]
Pantenburg, I [1 ]
机构：
[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷
关键词：
D O I：
10.1107/S0108270102014658
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In catena-poly[[[triaquacadmium(II)]-mu-acetylenedicarboxylato-kappa(4) O,O':O",O'''] hydrate], {[Cd(C4O4)(H2O)(3)].H2O}(n), the Cd-II atom is coordinated by two bidentate carboxylate groups and three water molecules, thus forming a sevenfold coordination polyhedron with all atoms located on general sites. These polyhedra are connected by the bifunctional acetylenedicarboxylate ligands, forming zigzag chains running parallel to [120]. Hydrogen bonds, which involve the non-coordinated water molecule, connect these chains to form a three-dimensional framework.
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收藏
页码：M483 / M484
页数：2
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