Imatinib intermediate as a two in one dual channel sensor for the recognition of Cu2+ and I- ions in aqueous media and its practical applications

被引:38
作者
Patil, Samadhan R. [1 ]
Nandre, Jitendra P. [1 ]
Jadhav, Devising [1 ]
Bothra, Shilpa [2 ]
Sahoo, S. K. [2 ]
Devi, Manisha [3 ]
Pradeep, Chullikkattil P. [3 ]
Mahulikar, Pramod P. [1 ]
Patil, Umesh D. [1 ]
机构
[1] North Maharashtra Univ, Sch Chem Sci, Jalgaon 425001, MS, India
[2] SV Natl Inst Technol, Dept Appl Chem, Surat 395007, Gujarat, India
[3] Indian Inst Technol, Sch Basic Sci, Kamand 175005, Himachal Prades, India
关键词
FLUORESCENT CHEMOSENSOR; IODIDE; COPPER; RECEPTOR; PROBE; DISORDERS; DISEASES; METALS; BASE; IRON;
D O I
10.1039/c4dt01516a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An imatinib intermediate, 6-methyl-N-[4-(pyridin-3-yl)pyrimidin-2-yl]benzene-1,3-diaminepyridopyrimidotoluidine (PPT-1), was developed for the colorimetric sensing of Cu2+ ions in aqueous solution. With Cu2+, the receptor PPT-1 showed a highly selective naked-eye detectable color change from colorless to red over the seventy other tested cations. The colorimetric sensing ability of PPT-1 was successfully utilized in the preparation of test strips and supported silica for the real samples analysis to detect Cu2+ ions from 100% aqueous environment. Moreover, the iodide-sensing ability of receptor PPT-1 was explored among the ten examined anions.
引用
收藏
页码:13299 / 13306
页数:8
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