Mixed-ligand complexes of Ni(II), Cu(II), and Zn(II) with 5-chlorosalicylaldehyde and β-diketones

被引：14

作者：

Prasad, RN ^{[1
]}

Agrawal, M ^{[1
]}

George, R ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2004年 / 34卷 / 05期

关键词：

mixed-ligand complexes; thin layer chromatography; magnetic moments; IR spectra; electronic spectra;

D O I：

10.1081/SIM-120037518

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed-ligand complexes of the types M(5-Clsa1)L and Ni(5-Clsal)L(H2O)(2) (where M = copper(II) or zinc(II), 5-Clsa1H = 5-chlorosalicylaldehyde and HL = 2,4-pentanedione, 1-phenyl-1,3-butanedione, or 1,3-diphenyl-1.3-propanedione) have been synthesized by I : I : I molar reactions of metal chlorides with 5-chlorosalicylaldehyde and beta-diketones. The resulting complexes have been characterized by elemental analyses, TLC, conductances, thermal analysis, magnetic moments, IR, electronic, and H-1 NMR spectra.

引用

页码：943 / 952

页数：10

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