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Multi-color microfluidic organic light-emitting diodes based on on-demand emitting layers of pyrene-based liquid organic semiconductors with fluorescent guest dopants
被引:50
作者:
Kasahara, Takashi
[1
]
Matsunami, Shigeyuki
[2
]
Edura, Tomohiko
[2
]
Ishimatsu, Ryoichi
[3
]
Oshima, Juro
[2
,4
]
Tsuwaki, Miho
[1
]
Imato, Toshihiko
[3
]
Shoji, Shuichi
[1
]
Adachi, Chihaya
[2
]
Mizuno, Jun
[5
]
机构:
[1] Waseda Univ, Dept Nanosci & Nanoengn, Shinjuku Ku, Tokyo 1698555, Japan
[2] Kyushu Univ, Ctr Organ Photon & Elect Res OPERA, Nishi Ku, Fukuoka 8190395, Japan
[3] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan
[4] Nissan Chem Ind Co Ltd, Mat Res Labs, Frontier Mat Res Dept, Funabashi, Chiba 2740052, Japan
[5] Waseda Univ, Inst Nanosci & Nanotechnol, Shinjuku Ku, Tokyo 1620041, Japan
关键词:
Microfluidic OLEDs;
Liquid OLEDs;
Liquid organic semiconductor;
Electro-microfluidic;
Energy transfer;
Liquid host;
FABRICATION;
DEVICES;
CELL;
D O I:
10.1016/j.snb.2014.09.101
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
In this study, we propose on-demand multi-color microfluidic organic light-emitting diodes (microfluidic OLEDs) using fluorescent guest emitter-doped liquid organic semiconductors. We use 1-pyrenebutyric acid 2-ethylhexyl ester (PLQ) not only for a greenish-blue liquid emitter, but also for a liquid host. 5,12-Diphenyltetracene (DPT), 5,6,11,12-tetraphenyltetracene (rubrene), and tetraphenyldibenzoperiflanthene (DBP) are doped into PLQ to obtain green, yellow, and red liquid emitters, respectively. Single-micrometer-thick SU-8-based microchannels sandwiched between an indium tin oxide (ITO) anode and a 3-aminopropyltriethoxysilane (APTES)-modified ITO cathode are fabricated on a glass substrate using photolithography and heterogeneous bonding techniques, and emitting layers are formed on-demand by simply injecting liquid emitters into the target microchannels. The microfluidic OLEDs with liquid emitters successfully exhibited multi-color electroluminescence (EL) emissions. Furthermore, the maximum luminance reached 26.0 cd/m(2) at 61 V for 2.5-mu m-thick microfluidic OLED with PLQ, and the decreased EL luminance was recovered by replacing the degraded emitting layer with a fresh liquid emitter. We expect that on-demand multi-color EL emissions and refreshable luminance features of the proposed microfluidic OLEDs will be highly promising technologies for future long-life light-emitting device applications. (C) 2014 Elsevier B.V. All rights reserved.
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页码:481 / 489
页数:9
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