Enhanced red emission on co-doping of divalent ions (M2+ = Ca2+, Sr2+, Ba2+) in YVO4:Eu3+ phosphor and spectroscopic analysis for its application in display devices

被引:68
作者
Kumari, Puja [1 ]
Manam, J. [1 ]
机构
[1] Indian Sch Mines, Dept Appl Phys, Dhanbad 826004, Bihar, India
关键词
Phosphor; Photoluminescence; Judd-Ofelt intensity parameter; CIE parameter; LUMINESCENCE PROPERTIES; PHOTOLUMINESCENCE; NANOPARTICLES; BEHAVIOR; TB3+;
D O I
10.1016/j.saa.2015.07.039
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
This paper reports the enhancement in photoluminescence due to the alkaline ions (M2+) co-doping in YVO4:Eu-3+ phosphors prepared by solid state reaction method. The as synthesized samples were found to have single phase tetragonal structure and the incorporation of dopant/codopant did not affect the crystal structure. The characteristic bands of Y-O and V O were located at 450 cm(-1) and 830 cm-1, respectively. The microscopic images exhibited the irregular morphology of the synthesized phosphor consisting of urn sized particles. Upon UV excitations, all phosphors showed intense red-orange emissions corresponding to the D-5(0) -> F-7(J1,2):Eu3+:Eu3+ transitions, and the emission intensity was further enhanced due to codoping. Divalent ions introduced radiative defect centers, which enhances the PL intensity significantly. The calculation of spectral parameters was done through Judd-Ofelt theory from emission spectra. The photometric characterizations and corresponding calculations indicated the suitability of the phosphor for display devices. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:109 / 118
页数:10
相关论文
共 46 条
[1]   Photoluminescence and structural properties of Ca3Y(VO4)3: RE3+ (=Sm3+, Ho3+ and Tm3+) powder phosphors for tri-colors [J].
Bandi, Vengala Rao ;
Grandhe, Bhaskar Kumar ;
Jayasimhadri, M. ;
Jang, Kiwan ;
Lee, Ho-Sueb ;
Yi, Soung-Soo ;
Jeong, Jung-Hyun .
JOURNAL OF CRYSTAL GROWTH, 2011, 326 (01) :120-123
[2]   Sintering and densification behavior of pure and alkaline earth (Ba2+, Sr2+ and Ca2+) substituted La2Mo2O9 [J].
Basu, Santanu ;
Devi, P. Sujatha ;
Bandyopadhyay, N. R. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2013, 33 (01) :79-85
[3]   ENERGY TRANSFER IN OXIDIC PHOSPHORS [J].
BLASSE, G .
PHYSICS LETTERS A, 1968, A 28 (06) :444-&
[4]   Combinatorial chemistry approach to searching phosphors for white light-emitting diodes in (Gd-Y-Bi-Eu)VO4 quaternary system [J].
Chen, Lei ;
Chen, Kuo-Ju ;
Hu, Shu-Fen ;
Liu, Shi .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (11) :3677-3685
[5]   Combinatorial Approach to the Development of a Single Mass YVO4:Bi3+,Eu3+ Phosphor with Red and Green Dual Colors for High Color Rendering White Light-Emitting Diodes [J].
Chen, Lei ;
Chen, Kuo-Ju ;
Lin, Chun-Che ;
Chu, Cheng-I ;
Hu, Shu-Fen ;
Lee, Min-Hung ;
Liu, Ru-Shi .
JOURNAL OF COMBINATORIAL CHEMISTRY, 2010, 12 (04) :587-594
[6]   An intense green emitting LiSrPO4:Eu2+, Tb3+ for phosphor-converted LED [J].
Chen, Yan ;
Wang, Jing ;
Zhang, Xinguo ;
Zhang, Gongguo ;
Gong, Menglian ;
Su, Qiang .
SENSORS AND ACTUATORS B-CHEMICAL, 2010, 148 (01) :259-263
[7]   Luminescence behavior of YVO4:Dy3+ phosphors with enhanced photoluminescence on co-doping Bi3+ ions [J].
Devi, Ch. Victory ;
Phaomei, Ganggam ;
Yaiphaba, N. ;
Singh, N. Rajmuhon .
JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 583 :259-266
[8]   A THEORY OF SENSITIZED LUMINESCENCE IN SOLIDS [J].
DEXTER, DL .
JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (05) :836-850
[9]   Charge compensation, electrical and dielectric behavior of lanthanum doped CaCu3Ti4O12 [J].
Dubey, Ashutosh Kumar ;
Singh, Prakash ;
Singh, Sindhu ;
Kumar, Devendra ;
Parkash, Om .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (09) :3899-3906
[10]   Excitation spectra and luminescence decay analysis of K+ compensated Dy3+ doped CaMoO4 phosphors [J].
Dutta, S. ;
Som, S. ;
Sharma, S. K. .
RSC ADVANCES, 2015, 5 (10) :7380-7387