An in situ approach to functionalize metal-organic frameworks with tertiary aliphatic amino groups

被引：12

作者：

Xi, Fu-Gui ^{[1
]}

Sun, Wei ^{[2
]}

Dong, Zhi-yun ^{[1
]}

Yang, Ning-Ning ^{[2
]}

Gong, Teng ^{[2
]}

Gao, En-Qing ^{[2
]}

机构：

[1] Xinzhou Teachers Univ, Dept Chem, Xinzhou 034000, Shanxi, Peoples R China

[2] East China Normal Univ, Coll Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 86期

关键词：

POST-SYNTHETIC MODIFICATION; COORDINATION; PERFORMANCE; CATALYSIS; OXIDATION; MIL-101; STORAGE; LIGAND; ENERGY; ROBUST;

D O I：

10.1039/d0cc05568a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-catalyzed reductive amination of formyl-containing linkers with N,N-dialkylformamide solvents is concomitant with the solvothermal coordination assembly, leading to novel MOFs functionalized with tertiary aliphatic amino groups. This illustrates a novel one-pot strategy to functionalize MOFs through in situ organic transformation. The UiO-66 MOFs partially functionalized with the amino groups are highly active heterogeneous catalysts for Knoevenagel condensation.

引用

页码：13177 / 13180

页数：4

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