1,3-Dinitro Alkanes: An Emerging Class of Bidentate Compounds Roberto Ballini,*[ a] Serena Gabrielli,[ a] and Alessandro Palmieri[ a]

被引：10
作者：
Ballini, Roberto [1 ]
Gabrielli, Serena [1 ]
Palmieri, Alessandro [1 ]
机构：
[1] Univ Camerino, Sch Sci & Technol, Div Chem, Green Chem Grp, I-62032 Camerino, Italy
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 2014卷 / 09期
关键词：
Synthetic methods; Cyclization; Michael addition; Nitro alkanes; ONE-POT SYNTHESIS; DIRECT MICHAEL ADDITION; BAYLIS-HILLMAN ADDUCTS; CONJUGATE ADDITION; USEFUL REAGENTS; NITRO-COMPOUNDS; FINE CHEMICALS; AQUEOUS-MEDIA; NITROALKANES; ACID;
D O I：
10.1002/ejoc.201301531
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1,3-Dinitro alkanes are an emerging class of nitro alkanes that act as bidentate nucleophilic species suited to undergo a variety of reactions with an array of electrophiles. The goal of this microreview is to demonstrate the synthetic potential of these nitro derivatives, reporting both (i) recent procedures for the convenient synthesis (symmetric and asymmetric) of 1,3-dinitro alkanes, and (ii) recent uses of these compounds as strategic starting materials for the preparation of a variety of important fine chemicals.
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页码：1805 / 1816
页数：12
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