Palladium-catalyzed carbonylative synthesis of alkynones from aryl iodides and phenylpropiolic acid employing formic acid as the CO source

被引：14
作者：
Li, Chong-Liang [1 ]
Zhang, Wan-Quan [1 ]
Qi, Xinxin [1 ]
Peng, Jin-Bao [1 ]
Wu, Xiao-Feng [1 ,2 ]
机构：
[1] Zhejiang Sci Tech Univ, Dept Chem, Xiasha Campus, Hangzhou 310018, Zhejiang, Peoples R China
[2] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 838卷
关键词：
Phenylpropiolic acid; Decarboxylation; Carbonylation; Palladium; Formic acid; Alkynones; CARBON-MONOXIDE SOURCE; TERMINAL ALKYNES; COUPLING REACTIONS; REDUCTIVE CARBONYLATION; PYRIMIDINE SYNTHESIS; SONOGASHIRA REACTION; IONIC LIQUIDS; O-IODOPHENOLS; CHLORIDES; CONVENIENT;
D O I：
10.1016/j.jorganchem.2017.03.028
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A palladium-catalyzed procedure for the decarboxylative-carbonylation of phenylpropiolic acid with iodobenzenes to the corresponding alkynones with formic acid as carbon monoxide source has been developed. Various alkynones were produced in moderate to good yields. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：9 / 11
页数：3
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