Electrochemical deposition of films of p-doped regioregular poly(3-hexylthiophene-2,5-diyl)

被引:8
作者
Yamamoto, T [1 ]
Kokubo, H [1 ]
机构
[1] Tokyo Inst Technol, Res Lab Resources Utilizat, Midori Ku, Yokohama, Kanagawa 2268503, Japan
关键词
D O I
10.1246/cl.1999.1295
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrochemically oxidative deposition of regioregular poly(3-hexylthiophene-2,5-diyl) gave a film in which p-doped polymer molecules took an ordered structure. According to the p-doping, the ordered structure of the neutral original polymer in the solid was changed. Conditions for the preparation of the film and electrically conducting properties of the film are described.
引用
收藏
页码:1295 / 1296
页数:2
相关论文
共 11 条
[1]  
Beckgaard K., 1980, SOLID STATE COMMUN, V33, P1119
[2]   REGIOCONTROLLED SYNTHESIS OF POLY(3-ALKYLTHIOPHENES) MEDIATED BY RIEKE ZINC - THEIR CHARACTERIZATION AND SOLID-STATE PROPERTIES [J].
CHEN, TA ;
WU, XM ;
RIEKE, RD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) :233-244
[3]   From monomers to pi-stacks. A comprehensive study of the structure and properties of monomeric, pi-dimerized, and pi-stacked forms of the cation radical of 3',4'-dibutyl-2,5''-diphenyl-2,2':5',2''-terthiophene [J].
Graf, DD ;
Duan, RG ;
Campbell, JP ;
Miller, LL ;
Mann, KR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (25) :5888-5899
[4]   ENHANCED ELECTRICAL-CONDUCTIVITY IN REGIOSELECTIVELY SYNTHESIZED POLY(3-ALKYLTHIOPHENES) [J].
MCCULLOUGH, RD ;
LOWE, RD .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (01) :70-72
[5]  
Mott NF., 1971, Electronic Processes in Non-crystalline Materials
[6]  
OGURA F, 1992, SULFUR REP, V11, P439
[7]   ELECTROCATALYSIS OF POLY(THIONINE)-MODIFIED ELECTRODES FOR OXIDATION OF REDUCED NICOTINAMIDE ADENINE-DINUCLEOTIDE [J].
OHSAKA, T ;
TANAKA, K ;
TOKUDA, K .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) :222-224
[8]   Organic electroluminescence device based on an electrodeposited poly(3-substituted thiophen) film [J].
Osaka, T ;
Komaba, S ;
Fujihana, K ;
Okamoto, N ;
Momma, T ;
Kaneko, N .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (02) :742-748
[9]   NEW ELECTROCHEMICALLY GENERATED ORGANIC CONDUCTING POLYMERS [J].
TOURILLON, G ;
GARNIER, F .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 135 (01) :173-178
[10]   Extensive studies on π-stacking of poly(3-alkylthiophene-2,5-diyl)s and poly(4-alkylthiazole-2,5-diyl)s by optical spectroscopy, NMR analysis, light scattering analysis, and X-ray crystallography [J].
Yamamoto, T ;
Komarudin, D ;
Arai, M ;
Lee, BL ;
Suganuma, H ;
Asakawa, N ;
Inoue, Y ;
Kubota, K ;
Sasaki, S ;
Fukuda, T ;
Matsuda, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (09) :2047-2058