Inhibition Effects of Chloroquinolines on Corrosion of Mild Steel in Hydrochloric Acid Solution

被引:4
作者
Shanbhag, A. V. [1 ]
Venkatesha, T. V. [2 ]
Praveen, B. M. [3 ]
Abd Hamid, S. B. [4 ]
机构
[1] SDM Coll, Dept Chem, Honavar 581334, Karnataka, India
[2] Kuvempu Univ, Dept PG Studies & Res Chem, Shankarghatta 577451, Karnataka, India
[3] Srinivas Sch Engn, Dept Chem, Mukka 575021, Karnataka, India
[4] Univ Malaya, IPS, Nanotechnol & Catalysis Res Ctr NANOCAT, Kuala Lumpur 53100, Malaysia
关键词
adsorption isotherm; corrosion inhibition; mild steel; chloroquinoline; mixed inhibitor; ZINC; DERIVATIVES; MEDIA;
D O I
10.1016/S1006-706X(14)60145-X
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The corrosion inhibition efficiencies of four compounds namely N-[(1E)-(2-chloroquinolin-3-yl) methylene]-N-phenylamine (CQMA), N-(1E)-(2-chloroquinolin-3-yl) methylene]-N-(4-fluorophenyl) amine (CQMFA), N-(4-chloro phenyl)-N-[(1E)-(2-chloroquinolin-3-yl) methylene] amine (CQMCA), and N-(4-bromo phenyl)-N-[(1E)-(2-chloroquinolin-3-yl) methylene] amine (CQMBA) on mild steel corrosion in hydrochloric acid media were investigated using mass loss, potentiodynamic polarization and electrochemical impedance spectroscopy. For all the studied inhibitors the inhibition efficiency values were found to increase with increasing concentration up to 5. 00 X 10(-4) mol center dot dm(-3). Scanning electron microscopic technique showed the formation of a thick film on the steel surface in the presence of inhibitors.
引用
收藏
页码:804 / 808
页数:5
相关论文
共 16 条
[1]  
Abd El-Rehim SSA, 1999, J APPL ELECTROCHEM, V29, P593
[2]   The corrosion inhibition of mild steel in acidic media by a new triazole derivative [J].
Bentiss, F ;
Lagrenee, M ;
Traisnel, M ;
Hornez, JC .
CORROSION SCIENCE, 1999, 41 (04) :789-803
[3]   Corrosion inhibition mechanism of carbon steel by sodium N,N-diethyl dithiocarbamate in hydrochloric acid solution [J].
Fan, HB ;
Wang, HL ;
Guo, XP ;
Zheng, JS .
ANTI-CORROSION METHODS AND MATERIALS, 2002, 49 (04) :270-276
[4]  
Gomma M. K., 1995, MATER CHEM PHYS, V39, P209
[5]  
Hayear R., 1981, J CHEM SOC P1, V1, P2509
[6]   ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY (EIS) OF CORROSION PROCESSES ON INHOMOGENEOUS SURFACES [J].
JUTTNER, K .
ELECTROCHIMICA ACTA, 1990, 35 (10) :1501-1508
[7]  
METHCOHN O, 1978, TETRAHEDRON LETT, P2045
[8]   Inhibition of phosphoric acid corrosion of zinc by organic onium compounds and their adsorption characteristics [J].
Morad, MS .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1999, 29 (05) :619-626
[9]  
Prabhu R.A., 2012, INT SCHOLARLY RES NO
[10]  
Praveen BM, 2009, INT J ELECTROCHEM SC, V4, P267