A Cd(II) coordination polymer with 5-ethoxy-isophthalate linker: synthesis, crystal structure, and fluorescent properties

被引：0
|
作者：
Chang Xin-Hong [1 ,2 ]
机构：
[1] Luoyang Normal Univ, Henan Key Lab Function Oriented Porous Mat, Luoyang, Peoples R China
[2] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2022年
关键词：
5-Ethoxy-isophthalic acid; 2; 2'-bipyridine; Cd(II) complex; crystal structure; ROOM-TEMPERATURE PHOSPHORESCENCE; MAGNETIC-PROPERTIES; ORGANIC FRAMEWORK; BUILDING-BLOCK; ACID; LUMINESCENT; SERIES; LIGANDS; 5-METHOXYISOPHTHALATE; COPPER(II);
D O I：
10.1080/24701556.2022.2068583
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Cd(II) metal-organic coordination polymer, {[Cd(eoip)(bipy)(H2O)]center dot H2O}(n) (1), (H(2)eoip = 5-ethoxy-isophthalic acid, bipy = 2,2'-bipyridine), was assembled under hydrothermal condition by the reactions of Cd(II) acetate with H(2)eoip and bipy. Complex 1 was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. Complex 1 was also characterized by TG and PXRD. The results reveal that the two carboxylic groups of each eoip ligand adopt chelate coordination modes to bridge adjacent Cd(II) ions to give a 1D chain along the b direction, the adjacent 1D chains are extended into a 3D supramolecular framework by hydrogen bonding. In addition, fluorescent properties of 1 were also investigated.
引用
收藏
页数：6
相关论文
共 50 条
  • [1] A Zn(II) coordination polymer with 5-ethoxy-isophthalate linker: synthesis, crystal structure, and fluorescent properties
    Chang, Xin-Hong
    Yan, Guang-Wei
    INORGANIC AND NANO-METAL CHEMISTRY, 2024, 54 (09) : 813 - 817
  • [2] A Zn(II) coordination polymer with 5-ethoxy-isophthalate linker: synthesis, crystal structure, and fluorescent properties
    Chang, Xin-Hong
    Yan, Guang-Wei
    INORGANIC AND NANO-METAL CHEMISTRY, 2024, 54 (09) : 813 - 817
  • [3] A Cu(II) Coordination Polymer with 5-Tert-butyl Isophthalate Linker: Synthesis, Crystal Structure, and Magnetic Properties
    Chang Xin-Hong
    Han Min-Le
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (12) : 1895 - 1900
  • [4] A Cu(Ⅱ) Coordination Polymer with 5-Tert-butyl Isophthalate Linker:Synthesis,Crystal Structure,and Magnetic Properties
    常新红
    韩民乐
    结构化学, 2015, 34 (12) : 1895 - 1900
  • [5] Hydrothermal Synthesis and Crystal Structure of Cd(II) Coordination Polymer
    Li, Bin
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (10) : 5497 - 5498
  • [6] Hydrothermal Synthesis and Crystal Structure of Cd(II) Coordination Polymer
    Xing, Jianxin
    ASIAN JOURNAL OF CHEMISTRY, 2010, 22 (08) : 6619 - 6621
  • [7] A Cd(II) Coordination Polymer Based on Mixed Ligands: Synthesis, Crystal Structure, and Properties
    Han, Shuai-Shuai
    He, Zi-Wei
    Li, Lei
    Chen, Shui-Sheng
    CRYSTALS, 2019, 9 (12):
  • [8] Lead(II) arenedisulfonate coordination polymer: Synthesis, crystal structure and properties
    Wang, Li
    Li, GuanFeng
    Liu, Mengjie
    Deng, Dongsheng
    Pei, Yamei
    Wang, Xinyi
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 35 : 192 - 194
  • [9] Synthesis, Crystal Structure, and Fluorescence Properties of a Zinc(II) Coordination Polymer
    Zhu, Kaiyue
    Gao, Yongchao
    Li, Gang
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2011, 41 (07) : 785 - 790
  • [10] A blue fluorescent Cd(II) coordination polymer with 3,5-diaminobenzoic acid ligand: synthesis, crystal structure and fluorescent property
    Ye, Q
    Chen, XB
    Song, YM
    Wang, XS
    Zhang, J
    Xiong, RG
    Fun, HK
    You, XZ
    INORGANICA CHIMICA ACTA, 2005, 358 (04) : 1258 - 1262
12345