Tri-Chain Hydrocarbon Surfactants as Designed Micellar Modifiers for Supercritical CO2

被引：55

作者：

Hollamby, Martin J. ^{[1
]}

Trickett, Kieran ^{[1
]}

Mohamed, Azmi ^{[1
]}

Cummings, Stephen ^{[1
]}

Tabor, Rico F. ^{[1
]}

Myakonkaya, Olesya ^{[1
]}

Gold, Sarah ^{[1
]}

Rogers, Sarah ^{[2
]}

Heenan, Richard K. ^{[2
]}

Eastoe, Julian ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 3DN, Avon, England

[2] STFC RAL, ISIS, Didcot OX11 0QX, Oxon, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 27期

基金：

英国工程与自然科学研究理事会;

关键词：

carbon dioxide; reverse micelles; small-angle neutron scattering; surfactants; sustainable chemistry; CARBON-DIOXIDE MICROEMULSIONS; ANGLE NEUTRON-SCATTERING; GREEN SOLVENTS; WATER; CHEMISTRY; MICELLIZATION; NANOPARTICLES; CO2-PHILES;

D O I：

10.1002/anie.200901543

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Getting their feet wet: Low-cost hydrocarbon surfactants act as fluid modifiers for supercritical carbon dioxide (scCO2). Increased terminal branching of the surfactant chains aids micelle formation (see middle picture:CO2 green), and more chains allows water to be incorporated (right, blue). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4993 / 4995

页数：3

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