Colloidal Route for Preparing Optical Thin Films of Nanoporous Metal-Organic Frameworks

被引:231
作者
Horcajada, Patricia [2 ]
Serre, Christian [2 ]
Grosso, David [1 ]
Boissiere, Cedric [1 ]
Perruchas, Sandrine [4 ]
Sanchez, Clement [1 ]
Ferey, Gerard [2 ,3 ]
机构
[1] Univ Paris 06, Lab Chim Mat Condensee Paris, CNRS, UMR 7574, F-75252 Paris 05, France
[2] Univ Versailles, Inst Lavoisier, CNRS, UMR 8180, F-78035 Versailles, France
[3] Inst Univ France, F-75005 Paris, France
[4] Ecole Polytech, Phys Mat Condensee Lab, CNRS, UMR 7643, F-91128 Palaiseau, France
关键词
GROWTH; SEPARATION; POROSITY; SOLIDS; MIL-53;
D O I
10.1002/adma.200801851
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Colloids of a highly flexible porous metal-organic framework (MOF) have been prepared using nontoxic and easily removable solvents. Furthermore, a simple dip-coating method for the preparation of optical-quality thin films of the MOF has been developed. The homogeneous thin film exhibits reversible flexibility, as has been proven by environmental ellipsometry.
引用
收藏
页码:1931 / 1935
页数:5
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