Ga2O3 Films for Photoelectrochemical Hydrogen Generation

被引:26
作者
Chang, Shoou-Jinn [1 ,2 ]
Wu, Ya-Ling [1 ,2 ]
Weng, Wen-Yin [1 ,2 ]
Lin, Yo-Hong [1 ,2 ]
Hsieh, Wei-Kang [1 ,2 ]
Sheu, Jinn-Kong [3 ]
Hsu, Cheng-Liang [4 ]
机构
[1] Natl Cheng Kung Univ, Adv Optoelect Technol Ctr, Inst Microelect, Tainan 701, Taiwan
[2] Natl Cheng Kung Univ, Adv Optoelect Technol Ctr, Dept Elect Engn, Tainan 701, Taiwan
[3] Natl Cheng Kung Univ, Dept Photon, Tainan 701, Taiwan
[4] Natl Univ Tainan, Dept Elect Engn, Tainan 700, Taiwan
关键词
OXIDE OHMIC CONTACTS; THIN-FILM; GAN PHOTOELECTRODES; VISIBLE-LIGHT; SOLAR-ENERGY; WATER; ELECTRODE; CELLS;
D O I
10.1149/2.0471409jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The authors report the use of RF sputtered Ga2O3 films prepared on SiO2/Si template to serve as the photoelectrode for photoelectrochemical (PEC) water splitting. It was found that photocurrent observed from the 900 degrees C-annealed Ga2O3 film was more than 3 orders of magnitude larger than its dark current at zero bias voltage. It was also found that no decomposition and/or corrosion occurred on the surface of the 900 degrees C-annealed Ga2O3 film. This suggests that Ga2O3 film has the potential to serve as a reliable photocathode for hydrogen generation. (C) 2014 The Electrochemical Society. All rights reserved.
引用
收藏
页码:H508 / H511
页数:4
相关论文
共 32 条
[11]   Photocatalysis and solar hydrogen production [J].
Kudo, Akihiko .
PURE AND APPLIED CHEMISTRY, 2007, 79 (11) :1917-1927
[12]   Heterogeneous photocatalyst materials for water splitting [J].
Kudo, Akihiko ;
Miseki, Yugo .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :253-278
[13]   Powering the planet: Chemical challenges in solar energy utilization [J].
Lewis, Nathan S. ;
Nocera, Daniel G. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (43) :15729-15735
[14]   Photoelectrochemical cells for solar hydrogen production: current state of promising photoelectrodes, methods to improve their properties, and outlook [J].
Li, Zhaosheng ;
Luo, Wenjun ;
Zhang, Minglong ;
Feng, Jianyong ;
Zou, Zhigang .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (02) :347-370
[15]   Mn-doped GaN as photoelectrodes for the photoelectrolysis of water under visible light [J].
Liu, Shu-Yen ;
Sheu, J. K. ;
Lin, Yu-Chuan ;
Tu, S. J. ;
Huang, F. W. ;
Lee, M. L. ;
Lai, W. C. .
OPTICS EXPRESS, 2012, 20 (19) :A678-A683
[16]   Immersed finger-type indium tin oxide ohmic contacts on p-GaN photoelectrodes for photoelectrochemical hydrogen generation [J].
Liu, Shu-Yen ;
Sheu, J. K. ;
Lee, M. L. ;
Lin, Yu-Chuan ;
Tu, S. J. ;
Huang, F. W. ;
Lai, W. C. .
OPTICS EXPRESS, 2012, 20 (06) :A190-A196
[17]   Hydrogen gas generation using n-GaN photoelectrodes with immersed Indium Tin Oxide ohmic contacts [J].
Liu, Shu-Yen ;
Lin, Yu-Chuan ;
Ye, Jhao-Cheng ;
Tu, S. J. ;
Huang, F. W. ;
Lee, M. L. ;
Lai, W. C. ;
Sheu, J. K. .
OPTICS EXPRESS, 2011, 19 (23) :A1196-A1201
[18]   Field-induced current modulation in epitaxial film of deep-ultraviolet transparent oxide semiconductor Ga2O3 [J].
Matsuzaki, K ;
Yanagi, H ;
Kamiya, T ;
Hiramatsu, H ;
Nomura, K ;
Hirano, M ;
Hosono, H .
APPLIED PHYSICS LETTERS, 2006, 88 (09)
[19]  
McIntyre N. S., 1978, QUANTITATIVE SURFACE, P83
[20]   Transparent and conductive multicomponent oxide films prepared by magnetron sputtering [J].
Minami, T .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1999, 17 (04) :1765-1772