Effects of nitrogen on the passivation of nickel-free high nitrogen and manganese stainless steels in acidic chloride solutions

被引：86

作者：

Fu, Yao ^{[1
]}

Wu, Xinqiang ^{[1
]}

Han, En-Hou ^{[1
]}

Ke, Wei ^{[1
]}

Yang, Ke ^{[1
]}

Jiang, Zhouhua ^{[2
]}

机构：

[1] Chinese Acad Sci, Inst Met Res, State key Lab Corros & Protect, Shenyang 110016, Peoples R China

[2] Northeastern Univ, Sch Met & Mat, Shenyang 110004, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2009年 / 54卷 / 16期

关键词：

Nitrogen; Stainless steel; Electrochemical impedance spectroscopy; Passivation; X-ray photoelectron spectroscopy; FE-CR ALLOYS; FREQUENCY-RESOLVED RRDE; 0.5 M H2SO4; CORROSION BEHAVIOR; PITTING CORROSION; AC-IMPEDANCE; SURFACE-COMPOSITION; ANODIC-DISSOLUTION; BINARY-ALLOYS; COLD WORK;

D O I：

10.1016/j.electacta.2009.02.024

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The role of nitrogen on the passivation of nickel-free high nitrogen and manganese stainless steels was investigated in 0.5 M H2SO4, 3.5% NaCl and 0.5 M H2SO4 + 0.5 M NaCl solutions using potentiodynamic polarization, electrochemical impedance spectroscopy and X-ray photoelectron spectroscopy techniques. The passive film stability was enhanced in 0.5 M H2SO4 and the pitting resistance was improved in 3.5% NaCl solution by more nitrogen addition. The influence of nitrogen extended the whole anodic polarization region in 0.5 M H2SO4 + 0.5 M NaCl solution, as demonstrated by the enhanced dissolution resistance, promoted adsorption and passivation process, improved film protection and pitting resistance with increasing nitrogen content. Possible mechanisms relating to the role of nitrogen in different potential regions were discussed. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：4005 / 4014

页数：10

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