High-Performance Ferroelectric Solid Solution Crystals: Pb(In1/2Nb1/2)O3-Pb(Zn1/3Nb2/3)O3-PbTiO3

被引：13
作者：
Li, Tao [1 ]
Long, Xifa [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Peoples R China
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2014年 / 97卷 / 09期
基金：
中国国家自然科学基金;
关键词：
MORPHOTROPIC-PHASE-BOUNDARY; FIELD-INDUCED STRAIN; SINGLE-CRYSTALS; PIEZOELECTRIC PROPERTIES; PYROELECTRIC PROPERTIES; DIELECTRIC-PROPERTIES; ELECTRICAL-PROPERTIES; GROWTH; BEHAVIOR; DIAGRAM;
D O I：
10.1111/jace.13035
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A series of regular shaped Pb(Zn1/3Nb2/3)O-3-based ternary ferroelectric single crystals (1-x)Pb(In1/2Nb1/2)O-3-0.33Pb(Zn1/3Nb2/3)O-3-xPbTiO(3) (PIN-PZN-PT) have been grown by means of the top-seeded solution growth method that prevented pyrochlore phase and promoted [001] or [111] growth. The nucleation and crystallization behavior of the Pb(Zn1/3Nb2/3)O-3-based ferroelectric single crystals differed from other relaxor-based ferroelectric single crystals was discovered. Di-/piezo-/ferro-/pyroelectric properties were characterized systematically. The PIN-PZN-PT single crystals showed large coercive fields E-c, high Curie temperature T-C and high pyroelectric coefficient P, presenting similar performance but better thermal stability compared with the PZN-PT single crystals, and making it a promising material for transducers and IR detectors in a wider temperature range.
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收藏
页码：2850 / 2857
页数：8
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