Use of electrostatic interaction for chiral recognition. Enantioselective complexation of anionic binaphthyls with protonated amino-beta-cyclodextrin

被引：20
作者：
Kano, K
Kitae, T
Takashima, H
机构：
[1] Dept. of Molec. Sci. and Technology, Faculty of Engineering, Doshisha University, Tanabe
来源：
JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1996年 / 25卷 / 1-3期
关键词：
D O I：
10.1007/BF01041578
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The studies using NMR and capillary zone electrophoresis clearly reveal that protonated 6(A)-amino-6(A)-deoxy-beta-cyclodextrin recognizes the chirality of anionic binaphthyl derivatives such as 1,1'-binaphthyl-2,2'-diyl phosphate and 1,1'-binaphthyl-2,2'-dicarboxylate through electrostatic interaction between the host and the guest and simultaneous inclusion.
引用
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页码：243 / 248
页数：6
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