Ambient-pressure molecular superconductor with a superlattice containing layers of tris(oxalato)rhodate enantiomers and 18-crown-6

被引：21

作者：

Martin, Lee ^{[1
]}

Morritt, Alexander L. ^{[1
]}

Lopez, Jordan R. ^{[1
]}

Akutsu, Hiroki ^{[2
]}

Nakazawa, Yasuhiro ^{[2
]}

Imajo, Shusaku ^{[2
]}

Ihara, Yoshihiko ^{[3
]}

机构：

[1] Nottingham Trent Univ, Sch Sci & Technol, Clifton Lane, Nottingham NG11 8NS, England

[2] Osaka Univ, Grad Sch Sci, Dept Chem, 1-1 Machikaneyama Cho, Toyonaka, Osaka 5600043, Japan

[3] Hokkaido Univ, Sch Sci, Dept Quantum & Condensed Matter Phys, Kita Ku, Sapporo, Hokkaido 0600810, Japan

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 02期

关键词：

BEDT-TTF; BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE; CONDUCTORS; SALTS;

D O I：

10.1021/acs.inorgchem.6b02708

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report a novel multilayered organic-inorganic hybrid material, beta ''-(BEDT-TTF)(2)[(H2O)-(NH4)(2)Rh(C2O4)(3)].18-crown-6. This is the first molecular superconductor to have a superlattice with layers of both BEDT-TTF and 18-crown-6 and also the first with the anion tris(oxalato)rhodate. This is the 2D superconductor with the widest gap between conducting layers, where only a single donor packing motif is observed (beta ''). The strong 2D nature of this system strongly suggests that the superconducting transition is a Kosterlitz-Thouless transition. A superconducting T-c of 2.7 K at ambient pressure was found by transport measurements and 2.5 K by magnetic susceptibility measurements.

引用

页码：717 / 720

页数：4

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